http://www.cnr.it/ontology/cnr/individuo/prodotto/ID55352
Potassium improved stability of Ni/MgO in the steam reforming of ethanol for the production of hydrogen for MCFC (Articolo in rivista)
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- Potassium improved stability of Ni/MgO in the steam reforming of ethanol for the production of hydrogen for MCFC (Articolo in rivista) (literal)
- Anno
- 2004-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.jpowsour.2003.12.032 (literal)
- Alternative label
*Frusteri F., *Freni S., *Chiodo V., *Spadaro L., *Bonura G. and **Cavallaro S. (2004)
Potassium improved stability of Ni/MgO in the steam reforming of ethanol for the production of hydrogen for MCFC
in Journal of power sources (Print); Elsevier B.V., Amsterdam (Belgio)
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- *Frusteri F., *Freni S., *Chiodo V., *Spadaro L., *Bonura G. and **Cavallaro S. (literal)
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- * Istituto CNR-TAE, Via Salita S. Lucia Sopra Contesse 5, I-98126 Messina, Italy
** Dipartimento di Chimica Industriale, Università di Messina, P.O. Box 29, S. Agata, I-98166 Messina, Italy (literal)
- Titolo
- Potassium improved stability of Ni/MgO in the steam reforming of ethanol for the production of hydrogen for MCFC (literal)
- Abstract
- The catalytic behavior of the bare and K-promoted 21% Ni/MgO catalyst in the ethanol steam reforming at MCFC operative conditions has been investigated. The effect of K loading (1-3wt.%) on the catalytic activity, stability and coking rate have been addressed. K addition stabilizes Ni catalyst mainly by depressing the metal sintering, while coke formation does not seem to be influenced by alkali addition. Endurance test (500h-1) performed at 20,000h-1 allows foresee a very long catalyst life in the case of practical application. High H2 productivity (5molH2/molfed ethanol) was obtained. A change in the electronic properties of the active phase accounts for the effect of K addition on the catalytic behavior of the Ni/MgO catalyst. (literal)
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