Stabilisation of composite LSFCO-CGO based anodes for methane oxidation in solid oxide fuel cells (Articolo in rivista)

Type
Label
  • Stabilisation of composite LSFCO-CGO based anodes for methane oxidation in solid oxide fuel cells (Articolo in rivista) (literal)
Anno
  • 2005-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.jpowsour.2004.12.040 (literal)
Alternative label
  • Sin A.; Kopnin E.; Dubitsky Y. ; Zaopo A. ; Aricò A.S. ; Gullo L.R. ; La Rosa D. ; Antonucci V. (2005)
    Stabilisation of composite LSFCO-CGO based anodes for methane oxidation in solid oxide fuel cells
    in Journal of power sources (Print); ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS, AMSTERDAM (Paesi Bassi)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Sin A.; Kopnin E.; Dubitsky Y. ; Zaopo A. ; Aricò A.S. ; Gullo L.R. ; La Rosa D. ; Antonucci V. (literal)
Pagina inizio
  • 68 (literal)
Pagina fine
  • 73 (literal)
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  • 145 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 145 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Pirelli Labs S.p.A., Viale Sarca 222, I-20126 Milan, Italy ; CNR-ITAE, Via Salita Santa Lucia Sopra Contesse 5, I-98125 Messina, Italy (literal)
Titolo
  • Stabilisation of composite LSFCO-CGO based anodes for methane oxidation in solid oxide fuel cells (literal)
Abstract
  • ALa0.6Sr0.4Fe0.8Co0.2O3-Ce0.8Gd0.2O1.9 (LSFCO-CGO) composite anode materialwas investigated for the direct electrochemical oxidation of methane in intermediate temperature solid oxide fuel cells (IT-SOFCs). A maximum power density of 0.17Wcm-2 at 800 oC was obtained with a methane-fed ceria electrolyte-supported SOFC. A progressive increase of performance was recorded during 140 h operation with dry methane. The anode did not show any structure degradation after the electrochemical testing. Furthermore, no formation of carbon deposits was detected by electron microscopy and elemental analysis. Alternatively, this perovskite material showed significant chemical and structural modifications after high temperature treatment in a dry methane stream in a packed-bed reactor. It is derived that the continuous supply of mobile oxygen anions from the electrolyte to the LSFCO anode, promoted by the mixed conductivity of CGO electrolyte at 800 oC, stabilises the perovskite structure near the surface under SOFC operation and open circuit conditions. (literal)
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