Poly(vinyl chloride) hollow-fiber membranes for ultrafiltration applications: Effects of the internal coagulant composition (Articolo in rivista)

Type
Label
  • Poly(vinyl chloride) hollow-fiber membranes for ultrafiltration applications: Effects of the internal coagulant composition (Articolo in rivista) (literal)
Anno
  • 2012-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/app.35220 (literal)
Alternative label
  • Q. F. Alsalhy, K. T. Rashid, W. A. Noori, S. Simone, A. Figoli, E. Drioli (2012)
    Poly(vinyl chloride) hollow-fiber membranes for ultrafiltration applications: Effects of the internal coagulant composition
    in Journal of applied polymer science (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Q. F. Alsalhy, K. T. Rashid, W. A. Noori, S. Simone, A. Figoli, E. Drioli (literal)
Pagina inizio
  • 2087 (literal)
Pagina fine
  • 2099 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 124 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • published online doi: 10.1002/app.35220 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Institute on Membrane Technology, National Research Council, c/o University of Calabria, Via P. Bucci Cubo 17/C, 87030, Rende (Cosanza), Italy School of Chemical Engineering, Oil and Gas Refinery Engineering Department, University of Technology, Alsinaa Street No. 52, B. O. 35010, Baghdad, Iraq Department of Chemical Engineering and Materials, University of Calabria, Via P. Bucci Cubo 42/A, 87030, Rende (Cosenza), Italy (literal)
Titolo
  • Poly(vinyl chloride) hollow-fiber membranes for ultrafiltration applications: Effects of the internal coagulant composition (literal)
Abstract
  • Poly(vinyl chloride) (PVC) hollow-fiber membranes were spun by a dry/wet phase-inversion technique from dopes containing 15 wt % PVC to achieve membranes with different pore sizes for ultrafiltration (UF) applications. The effects of the N,N-dimethylacetamide (DMAc) concentration in the internal coagulant on the structural morphology, separation performance, and mechanical properties of the produced PVC hollow fibers were investigated. The PVC membranes were characterized by scanning electron microscopy, average pore size, pore size distribution, void volume fraction measurements, and solubility parameter difference. Moreover, the UF experiments were conducted with pure water and aqueous solutions of poly(vinyl pyrrolidone) as feeds. The mechanical properties of the PVC hollow-fiber membranes were discussed in terms of the tensile strength and Young's modulus. It was found that the PVC membrane morphology changed from thin, fingerlike macrovoids at the inner edge to fully spongelike structure with DMAc concentration in the internal coagulant. The effective pores showed a wide distribution, between 0.2 and 1.1 ¼m, for the membranes prepared with H2O as the internal coagulant and a narrow distribution, between 0.114 and 0.135 ¼m, with 50 wt % DMAc. The results illustrate that the difference in the membrane performances was dependent on the DMAc concentration. (literal)
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