http://www.cnr.it/ontology/cnr/individuo/prodotto/ID55009
Hydrogen production by methanol steam reforming carried out in membrane reactor on Cu/Zn/Mg-based catalyst (Articolo in rivista)
- Type
- Label
- Hydrogen production by methanol steam reforming carried out in membrane reactor on Cu/Zn/Mg-based catalyst (Articolo in rivista) (literal)
- Anno
- 2008-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.cattod.2008.03.015 (literal)
- Alternative label
Basile, A., Tosti, S., Parmaliana, A., Iulianelli, A., Gallucci, F., Espro, C., Sporen, J. (2008)
Hydrogen production by methanol steam reforming carried out in membrane reactor on Cu/Zn/Mg-based catalyst
in Catalysis Today
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Basile, A., Tosti, S., Parmaliana, A., Iulianelli, A., Gallucci, F., Espro, C., Sporen, J. (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
- DOI: 10.1007/s11244-008-9128-6.
(literal)
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- a Institute on Membrane Technology, ITM-CNR, c/o University of Calabria, via P. Bucci, Cubo 17/C, 87030 Rende (CS), Italy
b Department of Industrial Chemistry, University of Messina, via Sperone 29, 98166 Messina, Italy
c ENEA, Unita` Tecnico Scientifica Fusione, C.R. ENEA Frascati, via E. Fermi 45, Frascati, 00044 Roma, Italy (literal)
- Titolo
- Hydrogen production by methanol steam reforming carried out in membrane reactor on Cu/Zn/Mg-based catalyst (literal)
- Abstract
- The methanol steam reforming (MSR) reaction was studied by using both a dense Pd-Ag membrane
reactor (MR) and a fixed bed reactor (FBR). Both the FBR and the MR were packed with a new catalyst
based on CuOAl2O3ZnOMgO, having an upper temperature limit of around 350 8C. A constant sweep gas
flow rate in counter-current mode was used in MR and the experiments were carried out by varying the
water/methanol feed molar ratio in the range 3/1-9/1 and the reaction temperature in the range 250-
300 8C. The catalyst shows high activity and selectivity towards the CO2 and the H2 formation in the
temperature range investigated. Under the same operative conditions, the MR shows higher conversions
than FBR and, in particular, at 300 8C and H2O/CH3OH molar ratio higher than 5/1 the MR shows complete
methanol conversion. (literal)
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