A novel model equation for the permeation of hydrogen in mixture with carbon-monoxide through Pd-Ag membranes (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• A novel model equation for the permeation of hydrogen in mixture with carbon-monoxide through Pd-Ag membranes (Articolo in rivista) (literal)

Anno

• 2008-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.seppur.2007.10.010 (literal)

Alternative label

• Barbieri G.; Scura F.; Lentini F.; De Luca G.; Drioli E.; (2008)
  A novel model equation for the permeation of hydrogen in mixture with carbon-monoxide through Pd-Ag membranes
  in Separation and purification technology (Print); Academic Press Elsevier, Inc., New York (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Barbieri G.; Scura F.; Lentini F.; De Luca G.; Drioli E.; (literal)

Pagina inizio

• 217 (literal)

Pagina fine

• 224 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.sciencedirect.com/science/article/pii/S1383586607004790 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 61 (literal)

Rivista

• Separation and purification technology (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 8 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 2 (literal)

Note

• Scopu (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• National Research Council, Institute for Membrane Technology (ITM-CNR), Via Pietro BUCCI, c/o The University of Calabria, cubo 17C, 87036 Rende CS, Italy The University of Calabria, Department of Chemical Engineering and Materials, cubo 44/A, Via Pietro BUCCI, 87030 Rende CS, Italy The University of Calabria, Via Pietro BUCCI, 87030 Rende CS, Italy (literal)

Titolo

• A novel model equation for the permeation of hydrogen in mixture with carbon-monoxide through Pd-Ag membranes (literal)

Abstract

• Hydrogen permeance decrease, owing to the covalent interaction of carbon monoxide with the Pd-Ag membrane surface, represents a considerable drawback, since this decreases the efficiency of the alloy membranes. This work proposes a novel Sieverts-Langmuir's model taking into account the mentioned adsorption. The proposed model equation, in order to take into account the fraction of the membrane surface not active for hydrogen permeation, introduces Langmuir's isotherm, which is the surface loading in the classical Sieverts' permeation equation. The evaluation of the ? parameter and the Langmuir affinity constant involved in the proposed model was carried out using experimental data measured using a 60 ?micron thick Pd-Ag commercial membrane at 647K (374 oC), up to a total pressure of 700 kPa. The presented model yields, in a parametric form, a quantitative assessment of hydrogen permeance decrease caused by the adsorption of gases on Pd-Ag membrane surfaces. Therefore, this novel Sieverts-Langmuir's equation models hydrogen permeation through Pd-Ag-based membranes in the presence of inhibitor gases such as CO. In addition, by ab initio evaluation of the ? and the Langmuir affinity constant, the proposed Sieverts-Langmuir's equation can identify a new membrane with better efficiency. (literal)

Editore

• Academic Press Elsevier, Inc. (Editore)

Prodotto di

• Institute on membrane technology (ITM) (Istituto)
• Membrane in Separazioni Gassose e Catalisi anche ad alta temperatura in processi di interesse industriale (PM.P02.007.007) (Modulo)

Autore CNR

• FRANCESCO SCURA (Persona)
• GIORGIO DE LUCA (Persona)
• GIUSEPPE BARBIERI (Unità di personale interno)
• ADELE BRUNETTI (Unità di personale interno)
• ENRICO DRIOLI (Unità di personale esterno)

Insieme di parole chiave

• Parole chiave di "A novel model equation for the permeation of hydrogen in mixture with carbon-monoxide through Pd-Ag membranes" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute on membrane technology (ITM) (Istituto)
• Membrane in Separazioni Gassose e Catalisi anche ad alta temperatura in processi di interesse industriale (PM.P02.007.007) (Modulo)

Autore CNR di

• GIUSEPPE BARBIERI (Unità di personale interno)
• GIORGIO DE LUCA (Persona)
• ENRICO DRIOLI (Unità di personale esterno)
• FRANCESCO SCURA (Persona)
• ADELE BRUNETTI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Separation and purification technology (Rivista)

Editore di

• Academic Press Elsevier, Inc. (Editore)

Insieme di parole chiave di

• Parole chiave di "A novel model equation for the permeation of hydrogen in mixture with carbon-monoxide through Pd-Ag membranes" (Insieme di parole chiave)