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Modelling and simulation of hydrogen permeation through supported Pd-alloy membranes with a multicomponent approach (Articolo in rivista)
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- Modelling and simulation of hydrogen permeation through supported Pd-alloy membranes with a multicomponent approach (Articolo in rivista) (literal)
- Anno
- 2008-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.ces.2008.01.009 (literal)
- Alternative label
Caravella, A.; Barbieri, G.; Drioli, E.; (2008)
Modelling and simulation of hydrogen permeation through supported Pd-alloy membranes with a multicomponent approach
in Chemical engineering science; Elsevier, Amsterdam (Paesi Bassi)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Caravella, A.; Barbieri, G.; Drioli, E.; (literal)
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- http://www.sciencedirect.com/science/article/pii/S0009250908000250 (literal)
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- ISI Web of Science (WOS) (literal)
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- a - Institute for Membrane Technology, ITM-CNR, Via Pietro Bucci, c/o The University of Calabria, Cubo 17/C, 87030 Rende, CS, Italy
b - Department of Chemical Engineering and Materials, The University of Calabria, Cubo 44/A, Via Pietro Bucci, 87030 Rende, CS, Italy (literal)
- Titolo
- Modelling and simulation of hydrogen permeation through supported Pd-alloy membranes with a multicomponent approach (literal)
- Abstract
- Hydrogen transport in Pd-based supported membranes was described by means of a model considering several elementary steps of the permeation process, improving what done by Ward and Dao [1999. Model of hydrogen permeation behavior in palladium membranes. Journal of Membrane Science 153 (2), 211-231] for self-supported membranes. The model includes the external mass transfer in the multicomponent gaseous phases on both sides of the membrane, described by the Stefan-Maxwell equations. The transport of the multicomponent mixture in the multilayered porous support was also considered and described by means of the dusty gas model, which takes into account Knudsen, Poiseuille and ordinary diffusion. The diffusion in the Pd-alloy layer is modeled by the irreversible thermodynamics theory, taking the hydrogen chemical potential as the driving force of the diffusion in the metallic bulk. The interfacial phenomena (adsorption, desorption, transition from Pd-based surface to Pd-based bulk and vice-versa) were described by the same expressions used by Ward and Dao (1999). Thicknesses of 1 and 10 ?m are considered for the Pd-alloy layer. The asymmetric support consists of five layers, each one characterized by a specific thickness and mean pore diameter. The model separates the permeation steps and consequently their influence, quantifying the relative resistances offered by each of them. Comparison with some experimental data in several conditions in the literature shows a good agreement. The developed tool is able to describe hydrogen transport through a supported Pd-based membrane, recognizing the rate-determining steps (e.g., diffusion in the metallic
bulk or in the porous support) involved in the permeation. (literal)
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