http://www.cnr.it/ontology/cnr/individuo/prodotto/ID54681
On The Mechanism of the Oxygen Transfer to Sulfoxides by Ti(IV)/Trialkanolamine/Peroxo Complexes. Evidence for a Metal Template Process (Articolo in rivista)
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- On The Mechanism of the Oxygen Transfer to Sulfoxides by Ti(IV)/Trialkanolamine/Peroxo Complexes. Evidence for a Metal Template Process (Articolo in rivista) (literal)
- Anno
- 2003-01-01T00:00:00+01:00 (literal)
- Alternative label
Bonchio M., Bortolini O., Licini G., Moro S., Nugent W.A. (2003)
On The Mechanism of the Oxygen Transfer to Sulfoxides by Ti(IV)/Trialkanolamine/Peroxo Complexes. Evidence for a Metal Template Process
in European journal of organic chemistry (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Bonchio M., Bortolini O., Licini G., Moro S., Nugent W.A. (literal)
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- Titolo
- On The Mechanism of the Oxygen Transfer to Sulfoxides by Ti(IV)/Trialkanolamine/Peroxo Complexes. Evidence for a Metal Template Process (literal)
- Abstract
- Oxidation of p-XC6H4SOMe (X = NC, F3C) by (alkylperoxo){tris[(2R)-2-hydroxy-2-phenylethyl]amine}titanium (2b ) has been shown to follow Michaelis-Menten kinetics demonstrating the occurrence of an intramolecular nucleophilic oxygen transfer to the TiIV-coordinated sulfoxide. The reaction of the titanium(IV) precursors 1 with sulfoxides has been studied by ESI-MS techniques together with ab initio calculations. (literal)
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