http://www.cnr.it/ontology/cnr/individuo/prodotto/ID54673
Electrospray Behavior of Lacunary Keggin-type Polyoxotungstates [XW11039]p-, (X=Si, P). Mass Spectrometric Evidence for a Concentration Dependent Incorporation of a MOn+ (M=W(VI), Mo(VI), V(V)) unit into the Polyoxometalate vacancy (Articolo in rivista)
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- Electrospray Behavior of Lacunary Keggin-type Polyoxotungstates [XW11039]p-, (X=Si, P). Mass Spectrometric Evidence for a Concentration Dependent Incorporation of a MOn+ (M=W(VI), Mo(VI), V(V)) unit into the Polyoxometalate vacancy (Articolo in rivista) (literal)
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- 2003-01-01T00:00:00+01:00 (literal)
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Bonchio M., Bortolini O., Conte V., Sartorel A. (2003)
Electrospray Behavior of Lacunary Keggin-type Polyoxotungstates [XW11039]p-, (X=Si, P). Mass Spectrometric Evidence for a Concentration Dependent Incorporation of a MOn+ (M=W(VI), Mo(VI), V(V)) unit into the Polyoxometalate vacancy
in European journal of inorganic chemistry (Print)
(literal)
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- Bonchio M., Bortolini O., Conte V., Sartorel A. (literal)
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- Titolo
- Electrospray Behavior of Lacunary Keggin-type Polyoxotungstates [XW11039]p-, (X=Si, P). Mass Spectrometric Evidence for a Concentration Dependent Incorporation of a MOn+ (M=W(VI), Mo(VI), V(V)) unit into the Polyoxometalate vacancy (literal)
- Abstract
- ESI-MS analysis provides a straightforward tool for the solution characterization of highly charged mono-lacunary Keggin-type polyoxotungstates Ñ-[XW11O39]p- (X = Si, P; p = 8, 7). Double and triple charged quasi-molecular ion peaks were identified on the bases of both the theoretical simulation of the isotopic cluster distributions and the fragmentation modes observed with MS/MS technique. This approach allows to characterize the inorganic polyanions transferred into the gas-phase with associated alkali metal cations (Li+, Na+). (literal)
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