Electrospray Behavior of Lacunary Keggin-type Polyoxotungstates [XW11039]p-, (X=Si, P). Mass Spectrometric Evidence for a Concentration Dependent Incorporation of a MOn+ (M=W(VI), Mo(VI), V(V)) unit into the Polyoxometalate vacancy (Articolo in rivista)

Type
Label
  • Electrospray Behavior of Lacunary Keggin-type Polyoxotungstates [XW11039]p-, (X=Si, P). Mass Spectrometric Evidence for a Concentration Dependent Incorporation of a MOn+ (M=W(VI), Mo(VI), V(V)) unit into the Polyoxometalate vacancy (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Alternative label
  • Bonchio M., Bortolini O., Conte V., Sartorel A. (2003)
    Electrospray Behavior of Lacunary Keggin-type Polyoxotungstates [XW11039]p-, (X=Si, P). Mass Spectrometric Evidence for a Concentration Dependent Incorporation of a MOn+ (M=W(VI), Mo(VI), V(V)) unit into the Polyoxometalate vacancy
    in European journal of inorganic chemistry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Bonchio M., Bortolini O., Conte V., Sartorel A. (literal)
Pagina inizio
  • 699 (literal)
Pagina fine
  • 704 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Titolo
  • Electrospray Behavior of Lacunary Keggin-type Polyoxotungstates [XW11039]p-, (X=Si, P). Mass Spectrometric Evidence for a Concentration Dependent Incorporation of a MOn+ (M=W(VI), Mo(VI), V(V)) unit into the Polyoxometalate vacancy (literal)
Abstract
  • ESI-MS analysis provides a straightforward tool for the solution characterization of highly charged mono-lacunary Keggin-type polyoxotungstates ƒÑ-[XW11O39]p- (X = Si, P; p = 8, 7). Double and triple charged quasi-molecular ion peaks were identified on the bases of both the theoretical simulation of the isotopic cluster distributions and the fragmentation modes observed with MS/MS technique. This approach allows to characterize the inorganic polyanions transferred into the gas-phase with associated alkali metal cations (Li+, Na+). (literal)
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