Silyl-Terminated Ethylene-co-Norbornene Copolymers by Organotitanium-Based Catalysts (Articolo in rivista)

Type
Label
  • Silyl-Terminated Ethylene-co-Norbornene Copolymers by Organotitanium-Based Catalysts (Articolo in rivista) (literal)
Anno
  • 2009-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/marc.200800559 (literal)
Alternative label
  • Marconi R.; Ravasio A.; Boggioni L.; Tritto I. (2009)
    Silyl-Terminated Ethylene-co-Norbornene Copolymers by Organotitanium-Based Catalysts
    in Macromolecular rapid communications
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Marconi R.; Ravasio A.; Boggioni L.; Tritto I. (literal)
Pagina inizio
  • 39 (literal)
Pagina fine
  • 44 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://onlinelibrary.wiley.com/doi/10.1002/marc.200800559/pdf (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 30 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 1 (literal)
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Marconi R., Ravasio A ., Boggioni L ., Tritto I. Istituto per lo Studio delle Macromolecole Via E. Bassini, 15 20133 Milano (literal)
Titolo
  • Silyl-Terminated Ethylene-co-Norbornene Copolymers by Organotitanium-Based Catalysts (literal)
Abstract
  • Ethylene (E) and norbornene (N) were copolymerized in the presence of PhSiH3 as chain-transfer agent with [Ti(?5: ?1-C5Me4SiMe2NBu t)(?-Me)2] precatalyst combined with [Ph3C][B(C6F5)4]. The silane was introduced at chain-ends of E-co-N copolymers with concomitant reinitiation of the growing polymer chain. The concentrations of the silane and polymer molecular weight are inversely correlated. The characteristic signals of -SiH2Ph chain-ends were observed by 1H NMR. The Si heteroatom is predominantly adjacent to ethylene units in E-co-N copolymers with high N content. (literal)
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