Ethene/4-Methyl-1-pentene Copolymers by Metallocene-Based Catalysts: Exhaustive Microstructural Characterization by (13)C NMR Spectroscopy (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Ethene/4-Methyl-1-pentene Copolymers by Metallocene-Based Catalysts: Exhaustive Microstructural Characterization by (13)C NMR Spectroscopy (Articolo in rivista) (literal)

Anno

• 2009-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/ma901226g (literal)

Alternative label

• Losio S. ; Boccia A. C. ; Boggioni L.; Sacchi M. C.; Ferro D.R. (2009)
  Ethene/4-Methyl-1-pentene Copolymers by Metallocene-Based Catalysts: Exhaustive Microstructural Characterization by (13)C NMR Spectroscopy
  in Macromolecules (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Losio S. ; Boccia A. C. ; Boggioni L.; Sacchi M. C.; Ferro D.R. (literal)

Pagina inizio

• 6964 (literal)

Pagina fine

• 6971 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.acs.org/doi/abs/10.1021/ma901226g (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 42 (literal)

Rivista

• Macromolecules (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 18 (literal)

Note

• Scopu (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Losio S. ; Boccia A. C. ; Boggioni L.; Sacchi M. C.; Ferro D.R. ISMAC CNR (literal)

Titolo

• Ethene/4-Methyl-1-pentene Copolymers by Metallocene-Based Catalysts: Exhaustive Microstructural Characterization by (13)C NMR Spectroscopy (literal)

Abstract

• The availability of a series of ethene/4-methyl-1-pentene copolymers spreading over a very broad range of chemical compositions, from about 1% up to 90% as 4-methyl-1-pentene molar content, paralleled by the heteronuclear 1H- 13C gradient-assisted 2D NMR techniques, has allowed for an improved peak assignment of their 13C NMR spectra. In particular, sequences richer in comonomer could be assigned, and the previous ambiguous assignment of S?? methylene carbon of the main chain was corrected. Starting from whole set of the previous and newly proposed assignments, a comprehensive check of consistency of the 13C NMR assignment can be completely fulfilled. From now on, the correct evaluation of the copolymer microstructure at tetrad level and of the copolymerization parameters of this interesting family of copolymers will be accessible. (literal)

Prodotto di

• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)
• Catalisi per nuove architetture macromolecolari e sistemi polimerici nanostrutturati e biomimetici (PM.P02.005.003) (Modulo)

Autore CNR

• SIMONA LOSIO (Persona)
• MARIA CARMELA SACCHI (Persona)
• DINO ROMANO FERRO (Unità di personale esterno)
• LAURA BOGGIONI (Persona)
• ANTONELLA CATERINA BOCCIA (Persona)

Insieme di parole chiave

• Keywords of "Ethene/4-Methyl-1-pentene Copolymers by Metallocene-Based Catalysts: Exhaustive Microstructural Characterization by (13)C NMR Spectroscopy" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• LAURA BOGGIONI (Persona)
• MARIA CARMELA SACCHI (Persona)
• SIMONA LOSIO (Persona)
• ANTONELLA CATERINA BOCCIA (Persona)
• DINO ROMANO FERRO (Unità di personale esterno)

Prodotto

• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)
• Catalisi per nuove architetture macromolecolari e sistemi polimerici nanostrutturati e biomimetici (PM.P02.005.003) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Macromolecules (Rivista)

Insieme di parole chiave di

• Keywords of "Ethene/4-Methyl-1-pentene Copolymers by Metallocene-Based Catalysts: Exhaustive Microstructural Characterization by (13)C NMR Spectroscopy" (Insieme di parole chiave)