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Thermal behavior of syndiotactic E-1,2 poly(3methyl-1,3-pentadiene) (Articolo in rivista)
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- Label
- Thermal behavior of syndiotactic E-1,2 poly(3methyl-1,3-pentadiene) (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.eurpolymj.2008.11.024 (literal)
- Alternative label
Bertini, F.; Canetti, M.; Ricci, G. (2009)
Thermal behavior of syndiotactic E-1,2 poly(3methyl-1,3-pentadiene)
in European Polymer Journal; PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD (Regno Unito)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Bertini, F.; Canetti, M.; Ricci, G. (literal)
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- ISI Web of Science (WOS) (literal)
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- ISMAC-CNR Istituto per lo Studio delle Macromolecole (literal)
- Titolo
- Thermal behavior of syndiotactic E-1,2 poly(3methyl-1,3-pentadiene) (literal)
- Abstract
- Syndiotactic E-1,2-poly(3-methyl-1,3-pentadiene) was synthesized with the catalyst system Fe(bipy)(2)Cl(2)-MAO. The thermal stability and kinetic parameters of degradation were determined by thermogravimetric analysis. The isothermal crystallization kinetics were described by means of the Avrami equation, which suggested a three-dimensional growth of crystalline units, developed by heterogeneous nucleation, followed by a secondary crystallization stage. Syndiotactic E-1,2-poly(3-methyl-1,3-pentadiene) isothermally crystallizes from the melt according to regime II of crystallization described by Lauritzen-Hoffman secondary nucleation theory. Non-isothermal crystallization kinetics were elaborated using different approaches. The equilibrium melting temperature was calculated. The kinetic and thermodynamic data were compared with those obtained from syndiotactic 1,2-poly(1,3-butadiene), which is the first example of 1,2 polydienes family. (literal)
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