Iron and Cobalt Complexes of 4-Alkyl-2,6-diiminopyridine Ligands: Synthesis and Ethylene Polymerization Catalysis (Articolo in rivista)

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Label
  • Iron and Cobalt Complexes of 4-Alkyl-2,6-diiminopyridine Ligands: Synthesis and Ethylene Polymerization Catalysis (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/ejic.200701220 (literal)
Alternative label
  • Cámpora J.; Naz A. M.; Palma P.; Rodríguez-Delgado A.; Álvarez E.; Tritto I.; Boggioni L. (2008)
    Iron and Cobalt Complexes of 4-Alkyl-2,6-diiminopyridine Ligands: Synthesis and Ethylene Polymerization Catalysis
    in European journal of inorganic chemistry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Cámpora J.; Naz A. M.; Palma P.; Rodríguez-Delgado A.; Álvarez E.; Tritto I.; Boggioni L. (literal)
Pagina inizio
  • 1871 (literal)
Pagina fine
  • 1879 (literal)
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  • http://onlinelibrary.wiley.com/doi/10.1002/ejic.200701220/pdf (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 2008 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 11 (literal)
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • J. Cámpora, A. M. Naz, P. Palma, A. Rodríguez-Delgado, E. Álvarez, Instituto de Investigaciones Químicas, Universidad de Sevilla –CSIC,c/ Americo Vespucio, 49. 41092, Seville, Spain L. Boggioni and I. Tritto ISMAC—MILANO (literal)
Titolo
  • Iron and Cobalt Complexes of 4-Alkyl-2,6-diiminopyridine Ligands: Synthesis and Ethylene Polymerization Catalysis (literal)
Abstract
  • A new methodology for selective alkylation of the 2,6-diiminopyridine (pdi) ligands allows the ready synthesis of new derivatives displaying 2-methyl-2-phenylpropyl (neophyl), benzyl, or allyl groups in the 4-position of the pyridine ring. A set of Fe and Co complexes containing the new ligands have been synthesized and fully characterized. The presence of 4-neophyl or -benzyl groups does not perturb the performance of the complexes as ethylene polymerization catalysts, but the introduction of the 4-allyl group leads to the production of higher molecular weight polymers. (literal)
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