http://www.cnr.it/ontology/cnr/individuo/prodotto/ID54393
Iron and Cobalt Complexes of 4-Alkyl-2,6-diiminopyridine Ligands: Synthesis and Ethylene Polymerization Catalysis (Articolo in rivista)
- Type
- Label
- Iron and Cobalt Complexes of 4-Alkyl-2,6-diiminopyridine Ligands: Synthesis and Ethylene Polymerization Catalysis (Articolo in rivista) (literal)
- Anno
- 2008-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/ejic.200701220 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Cámpora J.; Naz A. M.; Palma P.; Rodríguez-Delgado A.; Álvarez E.; Tritto I.; Boggioni L. (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://onlinelibrary.wiley.com/doi/10.1002/ejic.200701220/pdf (literal)
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- Rivista
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- Note
- Scopu (literal)
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- J. Cámpora, A. M. Naz, P. Palma, A. Rodríguez-Delgado, E. Álvarez, Instituto de Investigaciones Químicas, Universidad de Sevilla CSIC,c/ Americo Vespucio, 49. 41092, Seville, Spain
L. Boggioni and I. Tritto ISMACMILANO (literal)
- Titolo
- Iron and Cobalt Complexes of 4-Alkyl-2,6-diiminopyridine Ligands: Synthesis and Ethylene Polymerization Catalysis (literal)
- Abstract
- A new methodology for selective alkylation of the 2,6-diiminopyridine (pdi) ligands allows the ready synthesis of new derivatives displaying 2-methyl-2-phenylpropyl (neophyl), benzyl, or allyl groups in the 4-position of the pyridine ring. A set of Fe and Co complexes containing the new ligands have been synthesized and fully characterized. The presence of 4-neophyl or -benzyl groups does not perturb the performance of the complexes as ethylene polymerization catalysts, but the introduction of the 4-allyl group leads to the production of higher molecular weight polymers. (literal)
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