Electroluminescent Poly(fluorene-co-thiophene-S,S-dioxide): synthesis, characterisation and structure-property relationships?. (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Electroluminescent Poly(fluorene-co-thiophene-S,S-dioxide): synthesis, characterisation and structure-property relationships?. (Articolo in rivista) (literal)

Anno

• 2003-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1039/B208742A (literal)

Alternative label

• Mariacecilia Pasini, Silvia Destri, William Porzio, Chiara Botta and Umberto Giovanella (2003)
  Electroluminescent Poly(fluorene-co-thiophene-S,S-dioxide): synthesis, characterisation and structure-property relationships?.
  in Journal of materials chemistry (Print); Royal Society of Chemistry, Cambridge (Regno Unito)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Mariacecilia Pasini, Silvia Destri, William Porzio, Chiara Botta and Umberto Giovanella (literal)

Pagina inizio

• 807 (literal)

Pagina fine

• 812 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.rsc.org/en/Content/ArticleLanding/2003/JM/b208742a#!divAbstract (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 13 (literal)

Rivista

• Journal of materials chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 6 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto per lo Studio delle Macromolecole del C.N.R., via E. Bassini 15, 20133 Milano, Italy (literal)

Titolo

• Electroluminescent Poly(fluorene-co-thiophene-S,S-dioxide): synthesis, characterisation and structure-property relationships?. (literal)

Abstract

• A new copolymer, constituted by the regular alternation of a fluorene derivative with 1,1-dioxothiophene moiety, has been synthesised via Suzuki coupling. The molecular, thermal, structural, and photophysical characterisations have been performed. The material showed two dimensional order, enhanced by annealing; molecular modelling calculations afforded a consistent structural model accounting for the optical data. In comparison with both polyfluorenes and 1,1-dioxothiophene oligomers the unusual trend of photoluminescence quantum yield observed in solution and solid state was related to both a significant contribution of internal conversion in the deactivation process, in solution, and the formation of intra-chain hydrogen-bonds, due to the peculiar chain conformation, in solid state. LED devices showed the highest efficiency in the yellow region among similar copolymers containing both fluorene and 1,1-dioxothiophene functionalities. (literal)

Editore

• Royal Society of Chemistry (Editore)

Prodotto di

• Materiali multifunzionali organici e ibridi per l'energia (PM.P04.001.007) (Modulo)
• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)

Autore CNR

• MARIACECILIA PASINI (Persona)
• CHIARA BOTTA (Persona)
• SILVIA MARIA DESTRI (Unità di personale interno)
• WILLIAM UMBERTO PORZIO (Unità di personale interno)

Incoming links:

Autore CNR di

• MARIACECILIA PASINI (Persona)
• SILVIA MARIA DESTRI (Unità di personale interno)
• CHIARA BOTTA (Persona)
• WILLIAM UMBERTO PORZIO (Unità di personale interno)

Prodotto

• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)
• Materiali multifunzionali organici e ibridi per l'energia (PM.P04.001.007) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of materials chemistry (Rivista)

Editore di

• Royal Society of Chemistry (Editore)