http://www.cnr.it/ontology/cnr/individuo/prodotto/ID53773
Torsion Vapor Pressures and Sublimation Enthalpies of Aluminum Trifluoride and Aluminum Trichloride (Articolo in rivista)
- Type
- Label
- Torsion Vapor Pressures and Sublimation Enthalpies of Aluminum Trifluoride and Aluminum Trichloride (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/je8007167 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- BrunoBrunetti; Vincenzo Piacente; Paolo Scardala (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- P. Scardala: Università La Sapienza
V. Piacente: Università La Sapienza (literal)
- Titolo
- Torsion Vapor Pressures and Sublimation Enthalpies of Aluminum Trifluoride and Aluminum Trichloride (literal)
- Abstract
- The vapor pressures of solid AlF(3) and AlCl(3) were measured by the torsion-effusion method. Their temperature dependences fit the following equations: log(p/kPa) = (11.70 +/- 0.20) - (14 950 +/- 200)(T/K) (from (956 to 1113) K) and log(p/kPa) = (15.50 +/- 0.30) - (6200 +/- 200)(T/K) (from (321 to 378) K) for AlF(3) and AlCl(3), respectively. Treating the measured vapor pressures by the second- and third-law methods, the average standard enthalpies of the sublimation of 1 mol solid AlF(3) and AlCl(3) to AlF(3)(g) and Al(2)Cl(6)(g), Delta(sub)H degrees (298.15 K) = (301 +/- 4) kJ.mol(-1) and (59 +/- 2) kJ.mol(-1), respectively, were calculated. (literal)
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- Autore CNR
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