A mechanistic study on alcohol oxidations with oxygen catalysed by TPAP-doped ormosils in supercritical carbon dioxide (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• A mechanistic study on alcohol oxidations with oxygen catalysed by TPAP-doped ormosils in supercritical carbon dioxide (Articolo in rivista) (literal)

Anno

• 2005-01-01T00:00:00+01:00 (literal)

Alternative label

• S. Campestrini; M. Carraro; R. Ciriminna; M. Pagliaro; U. Tonellato (2005)
  A mechanistic study on alcohol oxidations with oxygen catalysed by TPAP-doped ormosils in supercritical carbon dioxide
  in Advanced synthesis & catalysis (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• S. Campestrini; M. Carraro; R. Ciriminna; M. Pagliaro; U. Tonellato (literal)

Pagina inizio

• 825 (literal)

Pagina fine

• 832 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 347 (literal)

Rivista

• Advanced synthesis & catalysis (Rivista)

Note

• ISI Web of Science (WOS) (literal)
• Scopus (literal)
• CAS reference linking service (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ISMN- Palermo; Università degli Studi di Padova (literal)

Titolo

• A mechanistic study on alcohol oxidations with oxygen catalysed by TPAP-doped ormosils in supercritical carbon dioxide (literal)

Abstract

• The heterogeneous oxidation of various alcohols with oxygen catalysed by TPAP-doped ormosils in scCO(2) at 75 degrees C and 22.0 MPa has been studied in detail. Sol-gel segregation of TPAP into the inner porosity of an organically modified silica (ormosil) xerogel along with the use of a reaction medium which does not dissolve the catalyst, prevents aggregation of oxidation-inactive ruthenium derivatives without the need of chemical tethering. Thus, at least 140 TONs may be obtained in the oxidation of primary alcohols with the formation of aldehydes as sole reaction products. Investigation of the oxidation mechanism shows that the catalytic process exhibits a first-order dependence on the amount of catalyst, a fractional order on the alcohol concentration and a negative order for oxygen pressures higher than 0.2 bar. Evidence is presented for an associative oxidation mechanism simultaneously involving TPAP, organic substrate and oxygen (literal)

Prodotto di

• Istituto per lo studio dei materiali nanostrutturati (ISMN) (Istituto)
• Nanomateriali multifunzionali per applicazioni chimiche avanzate (PM.P03.003.003) (Modulo)

Autore CNR

• ROSARIA CIRIMINNA (Unità di personale interno)
• MARIO PAGLIARO (Unità di personale interno)

Incoming links:

Autore CNR di

• MARIO PAGLIARO (Unità di personale interno)
• ROSARIA CIRIMINNA (Unità di personale interno)

Prodotto

• Istituto per lo studio dei materiali nanostrutturati (ISMN) (Istituto)
• Nanomateriali multifunzionali per applicazioni chimiche avanzate (PM.P03.003.003) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Advanced synthesis & catalysis (Rivista)