A nanoporous molecular magnet with reversible solvent-induced mechanical and magnetic properties. (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• A nanoporous molecular magnet with reversible solvent-induced mechanical and magnetic properties. (Articolo in rivista) (literal)

Anno

• 2003-01-01T00:00:00+01:00 (literal)

Alternative label

• Maspoch D 1, Ruiz-Molina D 2, Wurst K 3, Domingo N 4, Cavallini M 5, Biscarini F 6, Tejada J 7, Rovira C 8, Veciana J. 9 (2003)
  A nanoporous molecular magnet with reversible solvent-induced mechanical and magnetic properties.
  in Nature (Lond.)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Maspoch D 1, Ruiz-Molina D 2, Wurst K 3, Domingo N 4, Cavallini M 5, Biscarini F 6, Tejada J 7, Rovira C 8, Veciana J. 9 (literal)

Pagina inizio

• 190 (literal)

Pagina fine

• 195 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 2 (literal)

Rivista

• Nature (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• La rivista corretta è Nature Materials, il cui codice ISI non è stato trovato nell' All. 1 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1,2 8I9 - CSIC-Campus Universitari de Bellaterra, Cerdanyola, Spain 3- Institut für Allgemeine, Anorganische und Theoretische Chemie, Universität Innsbruck,Innsbruck, Austria 4,7 - Facultad de Física, Universitat de Barcelona, Barcelona, Spain 5,6- CNR-ISMN, Bologna, Italy (literal)

Titolo

• A nanoporous molecular magnet with reversible solvent-induced mechanical and magnetic properties. (literal)

Abstract

• Interest in metal-organic open-framework structures has increased enormously in the past few years because of the potential benefits of using crystal engineering techniques to yield nanoporous materials with predictable structures and interesting properties. Here we report a new efficient methodology for the preparation of metal-organic open-framework magnetic structures based on the use of a persistent organic free radical (PTMTC), functionalized with three carboxylic groups. Using this approach, we create an open-framework structure Cu3(PTMTC)2(py)6(CH3CH2OH)2(H2O), which we call MOROF-1, combining very large pores (2.8-3.1 nm) with bulk magnetic ordering. MOROF-1 shows a reversible and highly selective solvent-induced 'shrinking-breathing' process involving large volume changes (25-35%) that strongly influence the magnetic properties of the material. This magnetic sponge-like behaviour could be the first stage of a new route towards magnetic solvent sensors. (literal)

Prodotto di

• Istituto per lo studio dei materiali nanostrutturati (ISMN) (Istituto)

Autore CNR

• MASSIMILIANO CAVALLINI (Unità di personale interno)
• FABIO BISCARINI (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "A nanoporous molecular magnet with reversible solvent-induced mechanical and magnetic properties." (Insieme di parole chiave)

Incoming links:

Autore CNR di

• MASSIMILIANO CAVALLINI (Unità di personale interno)
• FABIO BISCARINI (Unità di personale interno)

Prodotto

• Istituto per lo studio dei materiali nanostrutturati (ISMN) (Istituto)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Nature (Rivista)

Insieme di parole chiave di

• Parole chiave di "A nanoporous molecular magnet with reversible solvent-induced mechanical and magnetic properties." (Insieme di parole chiave)