Evidence for magnetic interactions among magnetite nanoparticles dispersed in photoreticulated PEGDA-600 matrix (Articolo in rivista)

Type
Label
  • Evidence for magnetic interactions among magnetite nanoparticles dispersed in photoreticulated PEGDA-600 matrix (Articolo in rivista) (literal)
Anno
  • 2011-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1007/s11051-011-0249-7 (literal)
Alternative label
  • Allia P., Tiberto P., Coisson M., Chiolerio A., Celegato F., Vinai F., Sangermano M., Suber L., Marchegiani G. (2011)
    Evidence for magnetic interactions among magnetite nanoparticles dispersed in photoreticulated PEGDA-600 matrix
    in Journal of nanoparticle research
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Allia P., Tiberto P., Coisson M., Chiolerio A., Celegato F., Vinai F., Sangermano M., Suber L., Marchegiani G. (literal)
Pagina inizio
  • 5615 (literal)
Pagina fine
  • 5626 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 13 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • http://dx.doi.org/10.1007/s11051-011-0249-7 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Politecnico di Torino DISMIC, Corso Duca degli Abruzzi 24, 10125 Torino Italia INRIM, Electromagnetism, Strada delle Cacce 91, 10135 Torino Italia CNR-ISM, Area della Ricerca di Roma 1, P.O. Box 10, 00015 Monterotondo Italia (literal)
Titolo
  • Evidence for magnetic interactions among magnetite nanoparticles dispersed in photoreticulated PEGDA-600 matrix (literal)
Abstract
  • Magnetite nanoparticles having mean diameter of about 8 nm have been prepared by a thermo-chemical route. Different amounts (5 and 10% wt) of a stable dispersion of magnetite nanoparticles in n-hexane were added to polyethylene glycol diacrylate (PEGDA-600) oligomer containing 2% wt of radicalic photoinitiator. The homogenized mixture was poured on a silica glass substrate and the resulting film was photoreticulated in N2 atmosphere using a UV lamp. As a result, a polymer-based magnetic nanocomposite was obtained, where the magnetic nanoparticles are dispersed in the diamagnetic matrix, as checked by SEM. Morphology, composition, and size of as-prepared nanoparticles were checked by SEM and X-ray diffraction. The magnetic properties of magnetite nanoparticles prior to and after inclusion in the polymeric matrix have been studied by means of an alternating-gradient magnetometer (T interval: 10–300 K, HMAX: 18 kOe). FC-ZFC curves were obtained in the same temperature interval. The results show that the nanocomposites cannot be simply described as containing superparamagnetic particles undergoing an anisotropy-driven blocking and that collective magnetic interactions play a non-negligible role. Low-temperature hysteretic properties indicate that the polymeric matrix affects the effective anisotropy of magnetite nanoparticles. Dispersion of magnetite NPs in PEGDA has non-trivial consequences on their magnetic properties. (literal)
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