Comparison of the Structure and Magnetic Order in a Series of Layered Ni(II) Organophosphonates, Ni[(RPO3)(H2O)] (R = C6H5, CH3, C18H37) (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Comparison of the Structure and Magnetic Order in a Series of Layered Ni(II) Organophosphonates, Ni[(RPO3)(H2O)] (R = C6H5, CH3, C18H37) (Articolo in rivista) (literal)

Anno

• 2008-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/ic801124z (literal)

Alternative label

• Bauer E.M. (1); Bellitto C. (1); Righini G. (1); Colapietro M. (2); Portalone G. (2); Drillon M. (3); Rabu P. (3) (2008)
  Comparison of the Structure and Magnetic Order in a Series of Layered Ni(II) Organophosphonates, Ni[(RPO3)(H2O)] (R = C6H5, CH3, C18H37)
  in Inorganic chemistry
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Bauer E.M. (1); Bellitto C. (1); Righini G. (1); Colapietro M. (2); Portalone G. (2); Drillon M. (3); Rabu P. (3) (literal)

Pagina inizio

• 10945 (literal)

Pagina fine

• 10952 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 47 (literal)

Rivista

• Inorganic chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• http://dx.doi.org/10.1021/ic801124z (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1) CNR-Istituto di Struttura della Materia, Via Salaria Km. 29.3, I-00016 Monterotondo Stazione, Rome, Italy; 2) Department of Chemistry, University of Rome “Sapienza”, P.le A. Moro 5, 00185 Rome, Italy; 3) Institut de Physique et Chimie des Materiaux de Strasbourg, UMR7504 CNRS - ULP, 23 rue du Loess, 67034 Strasbourg, France (literal)

Titolo

• Comparison of the Structure and Magnetic Order in a Series of Layered Ni(II) Organophosphonates, Ni[(RPO3)(H2O)] (R = C6H5, CH3, C18H37) (literal)

Abstract

• The reaction of nickel chloride with phenyl phosphonic acid under hydrothermal conditions resulted in the isolation of yellow-green single crystals of Ni[(C6H5PO3)(H2O)]. The structure of the compound has been solved by X-ray single-crystal diffraction studies. Ni[(C6H5PO3)(H2O)] crystallizes in the orthorhombic space group Pmn21 and is isostructural with the Mn(II), Fe(II), and Co(II) analogues. It presents the typical features of the hybrid 2D structures, consisting of alternating inorganic and organic layers. The former are formed by six-coordinated nickel(II) ions bridged by oxygen atoms into the layers. The inorganic layers are capped by the phenyl phosphonate groups, with phenyl groups of two adjacent ligands forming a hydrophobic bilayer region, and van der Waals contacts are established between them. The magnetic properties investigated by means of dc and ac susceptibility measurements point to an AF exchange coupling between nearest neighboring Ni(II) ions. Below 5 K, the compound orders magnetically showing the typical features of a canted antiferromagnet. The magnetic behavior and magnetic dimensionality of Ni[(C6H5PO3)(H2O)] have been fully analyzed and compared to those of the Ni(II) parent compounds Ni[(RPO3)(H2O)] (where R = CH3, C18H37), which exhibit different symmetries of the inorganic layers and lengths of the R groups. (literal)

Prodotto di

• Institute of structure of matter (ISM) (Istituto)
• Materiali Ibridi Organici-Inorganici (MD.P06.004.001) (Modulo)

Autore CNR

• CARLO BELLITTO (Unità di personale interno)
• GUIDO RIGHINI (Persona)
• ELVIRA MARIA BAUER (Persona)

Incoming links:

Autore CNR di

• CARLO BELLITTO (Unità di personale interno)
• GUIDO RIGHINI (Persona)
• ELVIRA MARIA BAUER (Persona)

Prodotto

• Institute of structure of matter (ISM) (Istituto)
• Materiali Ibridi Organici-Inorganici (MD.P06.004.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganic chemistry (Rivista)