http://www.cnr.it/ontology/cnr/individuo/prodotto/ID52292
Elastic strains in silver clusters supported on MgO(100) (Articolo in rivista)
- Type
- Label
- Elastic strains in silver clusters supported on MgO(100) (Articolo in rivista) (literal)
- Anno
- 2003-01-01T00:00:00+01:00 (literal)
- Alternative label
Lagarde P., Colonna S., Flanke A.M., Jupille J. (2003)
Elastic strains in silver clusters supported on MgO(100)
in Surface science
(literal)
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- Lagarde P., Colonna S., Flanke A.M., Jupille J. (literal)
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- ISI Web of Science (WOS) (literal)
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- LURE, Bat. 209d, Centre Universitaire Paris-Sud, B.P. 34, 91898, Orsay Cedex, France
CNR-Istituto di Struttura della Materia, Via Fosso del Cavaliere 100, 00133, Roma, Italy
Groupe de Physique des Solides, Universités Paris 6 et 7, 75251, Paris Cedex 05, France (literal)
- Titolo
- Elastic strains in silver clusters supported on MgO(100) (literal)
- Abstract
- This work reports on the change in the silversilver interatomic distance dAgAg as a function of the coordination number for silver clusters supported on MgO(1 0 0) surfaces. Interatomic distances were determined by means of X-ray absorption spectroscopy (XAS) at the silver K-edge. For coordination number lower than 7 (below an average thickness equivalent to 1 ML), dAgAg is contracted with respect to the bulk parameter and scales with cluster size. For coordination numbers ranging between 7 and 10 (between 1 and 3 ML), dAgAg increases above the bulk value and shows a tendency to match the MgO(1 0 0) substrate. It then relaxes back to the bulk distance. Coordination numbers found herein successfully compare those derived from a model based on grazing incidence small angle X-ray scattering measurements. At low coverage, the XAS data measured by the total electron yield method exhibits diffraction peaks which are consistent with the presence of structurally coherent islands on the MgO substrate. (literal)
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