Phase development in the hardening process of two calcium phosphate bone cements: An energy dispersive X-ray diffraction study (Articolo in rivista)

Type
Label
  • Phase development in the hardening process of two calcium phosphate bone cements: An energy dispersive X-ray diffraction study (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.materresbull.2007.04.016 (literal)
Alternative label
  • Generosi A. (1); Smirnov V.V. (2); Rau J.V. (3); Rossi Albertini V. (1); Ferro D. (3); Barinov S.M. (2) (2008)
    Phase development in the hardening process of two calcium phosphate bone cements: An energy dispersive X-ray diffraction study
    in Materials research bulletin
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Generosi A. (1); Smirnov V.V. (2); Rau J.V. (3); Rossi Albertini V. (1); Ferro D. (3); Barinov S.M. (2) (literal)
Pagina inizio
  • 561 (literal)
Pagina fine
  • 571 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 43 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • http://dx.doi.org/10.1016/j.materresbull.2007.04.016 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • (1) CNR, Istituto di Struttura della Materia, I-00133 Rome, Italy; (2) Russian Acad Sci, Institute for Physical Chemistry of Ceramics, R-119361 Moscow, Russia (3) CNR, Istituto per lo Studio dei Materiali Nanostrutturati, I-00185 Rome, Italy (literal)
Titolo
  • Phase development in the hardening process of two calcium phosphate bone cements: An energy dispersive X-ray diffraction study (literal)
Abstract
  • This work was aimed at the application of an energy dispersive X-ray diffraction technique to study the kinetics of phase development during the setting and hardening reactions in two calcium phosphate bone cements. The cements under study are based on either tricalcium phosphate or tetracalcium phosphate initial solid phase, and a magnesium carbonate-phosphoric acid liquid phase as the hardening liquid. The application of the energy dispersive X-ray diffraction method allowed to collect the diffraction patterns from the cement pastes in situ starting from 1 min of the setting and hardening process. The only crystallized phase in both cements was apatite-like phase, the primary crystallization process proceeds during a few seconds of the setting reaction. Both the compressive strength and the pH value changes during the hardening period can be attributed to the transformations occurring in the intergranular X-ray amorphous phase. (literal)
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