Structure of a monolayer of Pd-diethynylbiphenyl deposited on chromium studied by total reflection EXAFS (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Structure of a monolayer of Pd-diethynylbiphenyl deposited on chromium studied by total reflection EXAFS (Articolo in rivista) (literal)

Anno

• 2004-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.snb.2003.12.032 (literal)

Alternative label

• D'Acapito F. (1); Fratoddi I. (2); D'amato R. (2); Russo M.V. (2); Contini G. (3); Davoli I. (4); Mobilio S. (5); Polzonetti G. (5); (2004)
  Structure of a monolayer of Pd-diethynylbiphenyl deposited on chromium studied by total reflection EXAFS
  in Sensors and actuators. B, Chemical (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• D'Acapito F. (1); Fratoddi I. (2); D'amato R. (2); Russo M.V. (2); Contini G. (3); Davoli I. (4); Mobilio S. (5); Polzonetti G. (5); (literal)

Pagina inizio

• 131 (literal)

Pagina fine

• 134 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 100 (literal)

Rivista

• Sensors and actuators. B, Chemical (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• (1) INFM, ESRF, GILDA, OGG, F-38043 Grenoble, France; (2) University of Rome La Sapienza, Department of Chemistry, I-00185 Rome, Italy; (3) CNR, ISM, I-00133 Rome, Italy; (4) University of Rome Tor Vergata, Department of Physics, INFM, I-00133 Rome, Italy; (5) University of Roma Tre, Department of Physics, I-00146 Rome, Italy (literal)

Titolo

• Structure of a monolayer of Pd-diethynylbiphenyl deposited on chromium studied by total reflection EXAFS (literal)

Abstract

• Poly-yne polymers containing transition metals are an interesting class of materials for their chemical and physical properties. In order to better understand the properties of such materials, a good knowledge of their structure is necessary. In this study we have determined the local structure around Pd in Pd-diethynylbiphenyl (Pd-DEBP, [Pd(PBU3)(2)C16H4](n)) polymer containing a diethynylbiphenyl unit as the organic spacer. Thin films of the material were deposited onto a Cr substrate and were studied by means of extended X-ray absorption structure spectroscopy (EXAFS) in total reflection mode. The bond lengths between Pd and its neighbors as well as the C-C distances in the linear chain are determined and compared with literature data reported for model complexes. (literal)

Prodotto di

• Superfici Funzionalizzate, Interfacce, Riconoscimento Molecolare e Catalisi (MD.P06.005.001) (Modulo)
• Institute of structure of matter (ISM) (Istituto)

Autore CNR

• GIORGIO CONTINI (Unità di personale interno)

Incoming links:

Autore CNR di

• GIORGIO CONTINI (Unità di personale interno)

Prodotto

• Institute of structure of matter (ISM) (Istituto)
• Superfici Funzionalizzate, Interfacce, Riconoscimento Molecolare e Catalisi (MD.P06.005.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Sensors and actuators. B, Chemical (Rivista)