Neutron powder diffraction of the layer organic-inorganic iron(II) methylphosphonate- hydride, Fe[(CD3PO3)(D2O)] (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Neutron powder diffraction of the layer organic-inorganic iron(II) methylphosphonate- hydride, Fe[(CD3PO3)(D2O)] (Articolo in rivista) (literal)

Anno

• 2008-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1061/j.jssc.2008.07.032 (literal)

Alternative label

• Léone P., Bellitto C., Bauer E.M., Righini G., André G., Bourée F. (2008)
  Neutron powder diffraction of the layer organic-inorganic iron(II) methylphosphonate- hydride, Fe[(CD3PO3)(D2O)]
  in Journal of solid state chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Léone P., Bellitto C., Bauer E.M., Righini G., André G., Bourée F. (literal)

Pagina inizio

• 3005 (literal)

Pagina fine

• 3009 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 181 (literal)

Rivista

• Journal of solid state chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• http://dx.doi.org/10.1016/j.jssc.2008.07.032 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Institut des Matériaux Jean Rouxel (IMN),Université de Nantes, CNRS, 2 Rue de la , Houssiniere, BP 32229, FR-44322 Nantes cedex 03, France; CNR, Istituto di Struttura della Materia, Via Salaria km 29.3, CP 10, I-000016 Monterotondo Stazione, Roma, Italy; Laboratoire Léon Brillouin, CEA-CNRS, CEA-Saclay, FR-91191 Gif-s-Yvette cedex, France (literal)

Titolo

• Neutron powder diffraction of the layer organic-inorganic iron(II) methylphosphonate- hydride, Fe[(CD3PO3)(D2O)] (literal)

Abstract

• The crystal and magnetic structures of the hybrid organic–inorganic layer compound Fe[(CD3PO3)(D2O)] have been studied by neutron powder diffraction as a function of temperature down to 1.5 K. The neutron diffraction pattern recorded at 200 K shows that the fully deuterated compound crystallizes in one of the two known forms of the undeuterated Fe[(CH3PO3)(H2O)]. The crystal structure is orthorhombic, space group Pmn21, with the following unit-cell parameters: a = 5.7095(1)AÚ , b = 8.8053(3)AÚ and c = 4.7987(1)AÚ ; Z = 2. The crystal structure remains unchanged on cooling from 200 to 1.5 K. Moreover, at low temperature, Fe[(CD3PO3)(D2O)] shows a commensurate magnetic structure (k = (0,0,0)). As revealed by bulk susceptibility measurements on Fe[(CD3PO3)(D2O)], the magnetic structure corresponds to a canted antiferromagnet with a critical temperature TN = 25 K. Neutron powder diffraction reveals that below TN = 23.5 K the iron magnetic moments in Fe[(CD3PO3)(D2O)] are antiferromagnetically coupled and oriented along the b-axis, perpendicular to the inorganic layers. No ferromagnetic component is observable in the neutron powder diffraction experiment, due to its too small value (<0.1 mB). (literal)

Prodotto di

• Institute of structure of matter (ISM) (Istituto)
• Materiali Ibridi Organici-Inorganici (MD.P06.004.001) (Modulo)

Autore CNR

• CARLO BELLITTO (Unità di personale interno)
• GUIDO RIGHINI (Persona)
• ELVIRA MARIA BAUER (Persona)

Insieme di parole chiave

• Parole chiave di "Neutron powder diffraction of the layer organic-inorganic iron(II) methylphosphonate- hydride, Fe[(CD3PO3)(D2O)]" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• CARLO BELLITTO (Unità di personale interno)
• GUIDO RIGHINI (Persona)
• ELVIRA MARIA BAUER (Persona)

Prodotto

• Institute of structure of matter (ISM) (Istituto)
• Materiali Ibridi Organici-Inorganici (MD.P06.004.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of solid state chemistry (Rivista)

Insieme di parole chiave di

• Parole chiave di "Neutron powder diffraction of the layer organic-inorganic iron(II) methylphosphonate- hydride, Fe[(CD3PO3)(D2O)]" (Insieme di parole chiave)