Dimorphism in Iron(II) methylphosphonate: Low-Temperature Crystal Structure and Temperature dependent Mössbauer Studies of a New Form of the Layered Weak ferromagnet Fe[(CH3PO3)(H2O)] (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Dimorphism in Iron(II) methylphosphonate: Low-Temperature Crystal Structure and Temperature dependent Mössbauer Studies of a New Form of the Layered Weak ferromagnet Fe[(CH3PO3)(H2O)] (Articolo in rivista) (literal)

Anno

• 2005-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.jssc.2005.01.020 (literal)

Alternative label

• Léone P., Palvadeau P., Boubekeur K., Meerschaut A., Bellitto C., Bauer E.M., Righini G., Fabritchnyi P. (2005)
  Dimorphism in Iron(II) methylphosphonate: Low-Temperature Crystal Structure and Temperature dependent Mössbauer Studies of a New Form of the Layered Weak ferromagnet Fe[(CH3PO3)(H2O)]
  in Journal of solid state chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Léone P., Palvadeau P., Boubekeur K., Meerschaut A., Bellitto C., Bauer E.M., Righini G., Fabritchnyi P. (literal)

Pagina inizio

• 1125 (literal)

Pagina fine

• 1132 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 178 (literal)

Rivista

• Journal of solid state chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• http://dx.doi.org/10.1016/j.jssc.2005.01.020 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Laboratoire de Chimie des Solides, Institut des Matériaux Jean Rouxel, UMR CNRS 6502, 2 Rue de la, Houssiniere, BP 33229, FR-44322 Nante Cedex 3, France; CNR, Istituto di Struttura della Materia, Via Salaria km 29.5, C.P. 10, I-00016 Monterotondo Stazione (Roma), Italy; Department of Chemistry, M.V. Lomonosov Moscow State University, 119899 Moscow V-234, Russia (literal)

Titolo

• Dimorphism in Iron(II) methylphosphonate: Low-Temperature Crystal Structure and Temperature dependent Mössbauer Studies of a New Form of the Layered Weak ferromagnet Fe[(CH3PO3)(H2O)] (literal)

Abstract

• A second form of the literature-known layered weak ferromagnet Fe[(CH3 PO3)(H2 O)] has been isolated. The crystal structure determination of this new form (2) has been carried out at , 200 and 130 K. It crystallizes in the orthorhombic space group Pmn 21 : a:5.7177(11), b=8.8093(18), C=4.8154(10) A , while form (1) crystallizes in the space group Pna 21 : a:17.58(2), b=4.814(1), 5.719(1) A. Mössbauer spectroscopy on form (2) has been performed in the temperature range 4–300 K; and, at , a drastic change in the quadrupole splitting (deltaE) and a broadening of the doublet components is noticed. But surprisingly, on cooling the crystal, no structural change is observed, which could account for the increase in .Below , 57 Fe spectra transform into hyperfine splitting patterns which reveal a magnetically ordered state in agreement with the results of earlier magnetic susceptibility studies. (literal)

Prodotto di

• Institute of structure of matter (ISM) (Istituto)
• Materiali Ibridi Organici-Inorganici (MD.P06.004.001) (Modulo)

Autore CNR

• ELVIRA MARIA BAUER (Persona)
• GUIDO RIGHINI (Persona)
• CARLO BELLITTO (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Dimorphism in Iron(II) methylphosphonate: Low-Temperature Crystal Structure and Temperature dependent Mössbauer Studies of a New Form of the Layered Weak ferromagnet Fe[(CH3PO3)(H2O)]" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• CARLO BELLITTO (Unità di personale interno)
• GUIDO RIGHINI (Persona)
• ELVIRA MARIA BAUER (Persona)

Prodotto

• Institute of structure of matter (ISM) (Istituto)
• Materiali Ibridi Organici-Inorganici (MD.P06.004.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of solid state chemistry (Rivista)

Insieme di parole chiave di

• Parole chiave di "Dimorphism in Iron(II) methylphosphonate: Low-Temperature Crystal Structure and Temperature dependent Mössbauer Studies of a New Form of the Layered Weak ferromagnet Fe[(CH3PO3)(H2O)]" (Insieme di parole chiave)