IRON SUBSTITUTED LITHIUM TITANIUM SPINELS: STRUCTURAL AND ELECTROCHEMICAL CHARACTERIZATION (Articolo in rivista)

Type
Label
  • IRON SUBSTITUTED LITHIUM TITANIUM SPINELS: STRUCTURAL AND ELECTROCHEMICAL CHARACTERIZATION (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Alternative label
  • Reale P., Panero S., Ronci F., Rossi Albertini V., Scrosati B. (2003)
    IRON SUBSTITUTED LITHIUM TITANIUM SPINELS: STRUCTURAL AND ELECTROCHEMICAL CHARACTERIZATION
    in Chemistry of materials
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Reale P., Panero S., Ronci F., Rossi Albertini V., Scrosati B. (literal)
Pagina inizio
  • 3437 (literal)
Pagina fine
  • 3442 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 15 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#descrizioneSinteticaDelProdotto
  • Il lavoro costituisce un'ulteriore progresso nel campo delle indagini in situ su celle a ione litio svolte tramite diffrazione di raggi X ad alta energia (presso la linea ID15b di ESRF, Grenoble). Con tale lavoro si evidenzia il ruolo che riveste la sostituizione di ioni Ti con ioni Fe, tanto sul rendimento elettrochimico della cella, quanto sulle variazioni strutturali del materiale catodico (spinello). (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR - ISM Università di Roma La Sapienza (literal)
Titolo
  • IRON SUBSTITUTED LITHIUM TITANIUM SPINELS: STRUCTURAL AND ELECTROCHEMICAL CHARACTERIZATION (literal)
Abstract
  • Iron substituted lithium titanium spinels with stoichiometry Li4/3-y/3FeyTi5/3-2y/3O4, were synthesized by a sol gel process. The attention was focused on two compositions, namely Li1.3Fe0.1Ti1.6O4 and Li1.25Fe0.25Ti1.5O4. The first spinel crystallizes in the typical space group while the second adopts the P4332 symmetry. The two spinels were tested as electrodes in lithium cells. It was observed that these electrodes are capable to insert up to 1.4-1.6 lithium ion equivalents per formula unit and to cycle reversibly 160-180mAh/g at C/5 in the 2.9-0.2V potential range. The electrochemical responses are quite different from that of pure Li4/3Ti5/3O4, since the lithium insertion (deinsertion) processes evolve through several one-phase and two-phase steps, clearly involving the reduction (oxidation) of both titanium (IV) and iron (III) which occupy different framework positions. The electrochemical discharge mechanism of the two spinel electrodes was investigated by combining electrochemical tests with in situ diffraction measurements carried out using high energy synchrotron radiation. (literal)
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