http://www.cnr.it/ontology/cnr/individuo/prodotto/ID51986
In Situ Very-High-Energy Diffraction Studies of Thermal Decomposition of Transition Metal Trifluorides (Articolo in rivista)
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- In Situ Very-High-Energy Diffraction Studies of Thermal Decomposition of Transition Metal Trifluorides (Articolo in rivista) (literal)
- Anno
- 2003-01-01T00:00:00+01:00 (literal)
- Alternative label
Rau J. V., Rossi Albertini V., Chilingarov N.S., Di Michiel M., Colonna S., Ioffe I.N., Sidorov L.N. (2003)
In Situ Very-High-Energy Diffraction Studies of Thermal Decomposition of Transition Metal Trifluorides
in Bulletin of the Chemical Society of Japan
(literal)
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- Rau J. V., Rossi Albertini V., Chilingarov N.S., Di Michiel M., Colonna S., Ioffe I.N., Sidorov L.N. (literal)
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- Istituto di Struttura della Materia (literal)
- Titolo
- In Situ Very-High-Energy Diffraction Studies of Thermal Decomposition of Transition Metal Trifluorides (literal)
- Abstract
- The thermal decomposition of transition metal trifluorides MF3 (M = Mn, Fe, Co) was studied by collecting sequences of very-high-energy (89 keV) synchrotron radiation diffraction patterns. The real-time evolution of the crystal lattices was followed as a function of temperature and it was observed that the transition from MF3 to MF2 is generally accompanied by the formation of intermediate short-living phases M2F5. One of them Co2F5 is a phase which had never been observed before. (literal)
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