Reversible Interconversion between Luminescent Isomeric Metal-Organic Frameworks of [Cu4I4(DABCO)2] (DABCO=1,4-Diazabicyclo [2.2.2]octane) (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Reversible Interconversion between Luminescent Isomeric Metal-Organic Frameworks of [Cu4I4(DABCO)2] (DABCO=1,4-Diazabicyclo [2.2.2]octane) (Articolo in rivista) (literal)

Anno

• 2010-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/chem.200900743 (literal)

Alternative label

• D. Braga; L. Maini; P. P. Mazzeo; B. Ventura (2010)
  Reversible Interconversion between Luminescent Isomeric Metal-Organic Frameworks of [Cu4I4(DABCO)2] (DABCO=1,4-Diazabicyclo [2.2.2]octane)
  in Chemistry (Weinh., Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• D. Braga; L. Maini; P. P. Mazzeo; B. Ventura (literal)

Pagina inizio

• 1553 (literal)

Pagina fine

• 1559 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 16 (literal)

Rivista

• Chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• DOI: 10.1002/chem.200900743 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 5 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1. Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy 2. CNR, ISOF, I-40129 Bologna, Italy (literal)

Titolo

• Reversible Interconversion between Luminescent Isomeric Metal-Organic Frameworks of [Cu4I4(DABCO)2] (DABCO=1,4-Diazabicyclo [2.2.2]octane) (literal)

Abstract

• The metal-organic frameworks (MOF) of cluster [Cu(4)I(4)-(DABCO)(2)] (DABCO=1,4-diazabicyclo[2.2.2]octane) have been prepared and characterized as two different crystalline forms, I and II. Form I is obtained by reaction of DABCO and Cut in aqueous solution or by solvothermal reaction, while form II is obtained by reacting DABCO and Cut in acetonitrile. Their luminescence properties in the solid state have been analyzed at room temperature and at 77 K. MOF II has bright emission with a maximum at 556 nm that shifts bathochromically at low temperature in conjunction with a marked change in the colour of the emission. The emission of MOF I has a maximum at 580 nm and a less pronounced temperature dependence. The peculiar luminescence properties of the two isomers have been interpreted by utilising current knowledge on the excited states properties of Cut cubane clusters. The two isomers exhibit it high degree of porosity and can release the disordered solvent molecules trapped in the channels, whilst preserving the crystal structure. Isomer I can be converted into II on exposure to acetonitrile or methanol vapour, whereas Ill reverts to I when heated in a closed pan at 250 degrees C. (literal)

Prodotto di

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Materiali Avanzati per la COnversione di energia Luminosa (MACOL) (PM.P04.010.001) (Modulo)

Autore CNR

• BARBARA VENTURA (Persona)

Insieme di parole chiave

• Keywords of "Reversible Interconversion between Luminescent Isomeric Metal-Organic Frameworks of [Cu4I4(DABCO)2] (DABCO=1,4-Diazabicyclo [2.2.2]octane)" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Materiali Avanzati per la COnversione di energia Luminosa (MACOL) (PM.P04.010.001) (Modulo)

Autore CNR di

• BARBARA VENTURA (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Chemistry (Rivista)

Insieme di parole chiave di

• Keywords of "Reversible Interconversion between Luminescent Isomeric Metal-Organic Frameworks of [Cu4I4(DABCO)2] (DABCO=1,4-Diazabicyclo [2.2.2]octane)" (Insieme di parole chiave)