Color-variable highly efficient organic electrophosphorescent diodes manipulating molecular exciton and excimer emissions (Articolo in rivista)

Type
Label
  • Color-variable highly efficient organic electrophosphorescent diodes manipulating molecular exciton and excimer emissions (Articolo in rivista) (literal)
Anno
  • 2009-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1063/1.3086900 (literal)
Alternative label
  • M. Cocchi, J. Kalinowski, V. Fattori, J. A. Gareth Williams, and L. Murphy (2009)
    Color-variable highly efficient organic electrophosphorescent diodes manipulating molecular exciton and excimer emissions
    in Applied physics letters
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • M. Cocchi, J. Kalinowski, V. Fattori, J. A. Gareth Williams, and L. Murphy (literal)
Pagina inizio
  • 073309 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 94 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 3 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 7 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • M. Cocchi, V. Fattori; CNR, Inst Organ Photosynth & Photoreact, I-40129 Bologna, Italy J. Kalinowski; Gdansk Univ Technol, PL-80952 Gdansk, Poland JAG Williams, L Murphy; Univ Durham, Dept Chem, Durham DH1 3LE, England (literal)
Titolo
  • Color-variable highly efficient organic electrophosphorescent diodes manipulating molecular exciton and excimer emissions (literal)
Abstract
  • A simple way of tuning the emission color and electroluminescence efficiency from vacuum-deposited emitters of phosphorescent organic light emitting diodes (LEDs) is demonstrated. For each color a single-emissive layer consisting of a blend of two materials, one of Pt(N(and)C(and)N) complex series [where (N(and)C(and)N)=di(2-pyridinyl)benzene-based tridentate ligands] as either the low-concentration bluish green (molecular) phosphorescence emitter or high-concentration red (excimer) phosphorescence emitter, and (4,4('),4(')-tris(N-carbazolyl-triphenylamine) as the host was employed. By adjusting the relative amount of blue and red emissive species, the color of the light emission was tuned from bluish green through green and white up to red. Very high external quantum efficiency (up to 18.3 +/- 0.5%) and current efficiency (up to 44.8 +/- 0.5 cd/A) at similar to 500 cd/m(2) four-layer devices were achieved with white and greenish light emitting layers, respectively. It is found that the introduction of electron-withdrawing fluorine atoms at the central ring and electron-donating groups at the lateral rings of the Pt complex leads to a blueshift in the molecular and excimer emissions, respectively. This allows to refine colors and optimize the efficiency of the LEDs by selecting suitable substituents. (literal)
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