Mixing of molecular exciton and excimer phosphorescence to tune color and efficiency of organic LEDs (Articolo in rivista)

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Label
  • Mixing of molecular exciton and excimer phosphorescence to tune color and efficiency of organic LEDs (Articolo in rivista) (literal)
Anno
  • 2010-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.orgel.2009.11.017 (literal)
Alternative label
  • M. Cocchi; J. Kalinowski; L. Murphy; J.A. G. Williams; V. Fattori (2010)
    Mixing of molecular exciton and excimer phosphorescence to tune color and efficiency of organic LEDs
    in Organic electronics (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • M. Cocchi; J. Kalinowski; L. Murphy; J.A. G. Williams; V. Fattori (literal)
Pagina inizio
  • 388 (literal)
Pagina fine
  • 396 (literal)
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  • 11 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 9 (literal)
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  • 3 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1. Gdansk Univ Technol, PL-80233 Gdansk, Poland 2. Natl Res Council Italy ISOF CNR, Inst Organ Synth & Photoreact, I-40129 Bologna, Italy 3. Univ Durham, Dept Chem, Durham DH1 3LE, England (literal)
Titolo
  • Mixing of molecular exciton and excimer phosphorescence to tune color and efficiency of organic LEDs (literal)
Abstract
  • We report highly efficient, variable-color light-emitting diodes (LEDs) realized via mixing of molecular exciton and excimer phosphorescent emissions from a new organic phosphor platinum N boolean AND C(2)boolean AND N-[1,3-di(4-methoxy-pyrid-2-yl)-4,6-difluorobenzene] chloride (PtL(26)Cl), a member of the Pt(N boolean AND C boolean AND N) complex series, where N boolean AND C boolean AND N represents a cyclometallating tridentate ligand based on 1,3-dipyridylbenzene, L. PtL(26)Cl-doped TCTA blends [TCTA = 4,4',4 ''-tris(N-carbazolyl-triphenylamine)] have been used as either the low-concentration bluish-green (molecular) phosphorescence emitter or high-concentration red (excimer) phosphorescence emitter. By adjusting the relative amount of blue and red emissive species, the color of the light emission was tuned from bluish-green through green and white up to red. The concentration-optimized devices can easily reach high brightness up to B = 10,000 cd/m(2), achieving extremely high external quantum efficiency (EQE) up to 20% at low-current densities (<10(-2) mA/cm(2)) and up to 17% at B = 500 cd/m(2). High purity white light emission [CIE coordinates (x = 0.34, y = 0.35)] was realized at this B, QE = 11.5%, power efficiency of 6.8 lm/W and color rendering index (CRI) = 74, though CRI = 81 has been achieved with CIE coordinates (x = 0.42, y = 0.38). The reported performance data are among the best achievements reported for color and white emission organic LEDs. (C) 2009 Elsevier B.V. All rights reserved. (literal)
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