http://www.cnr.it/ontology/cnr/individuo/prodotto/ID51204
Fabrication of Ag nanoparticles by g-irradiation: Application to surface-enhanced Raman spectroscopy of fungicides (Articolo in rivista)
- Type
- Label
- Fabrication of Ag nanoparticles by g-irradiation: Application to surface-enhanced Raman spectroscopy of fungicides (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.colsurfa.2009.01.018 (literal)
- Alternative label
Torreggiani, A. (2); Tamba, M. (2); D'Angelantonio, M. (2); Jurasekova, Z. (1); Garcia-Ramos, J. V. (1); Sanchez-Cortes, S. (1) (2009)
Fabrication of Ag nanoparticles by g-irradiation: Application to surface-enhanced Raman spectroscopy of fungicides
in Colloids and surfaces. A, Physicochemical and engineering aspects (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Torreggiani, A. (2); Tamba, M. (2); D'Angelantonio, M. (2); Jurasekova, Z. (1); Garcia-Ramos, J. V. (1); Sanchez-Cortes, S. (1) (literal)
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- Scopu (literal)
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- (1) Instituto de Estructura de la Materia - CSIC; (2) Istituto ISOF (CNR) - (literal)
- Titolo
- Fabrication of Ag nanoparticles by g-irradiation: Application to surface-enhanced Raman spectroscopy of fungicides (literal)
- Abstract
- This paper is concerned with the surface enhanced Raman scattering (SERS) activity of silver colloids
obtained by a radiolytic method. Ag nanoparticles were successfully prepared by ?-radiolysis
of Ag+ aqueous solution containing t-BuOH or i-PrOH at room temperature without the addition of
aggregating or stabilizing substances. The metal colloids were characterised by UV/vis spectroscopy
and scanning electron microscopy. Many experimental conditions were tested (i.e. Ag+ concentration,
dose and oOH scavenger alcohol) in order to obtain the best controlled size of nanoparticles as well
as the high stability of colloidal silver with time. The use of relatively low irradiation doses and Ag+
concentrations allowed to obtain very stable suspensions of Ag nanoparticles without adding any
colloid stabiliser, a source of further spurious bands in the Raman spectra. The suitability of the ?-
irradiated colloids in SERS spectroscopy was tested by using thiram, a known fungicide. Micro-SERS
and SERS spectra of good quality were achieved at very low concentration of adsorbate, without the
overlapping of impurities normally present in conventional citrate colloidal suspensions of Ag nanoparticles. (literal)
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