On the actual EPR detection of thioacyl radicals (Articolo in rivista)

Type
Label
  • On the actual EPR detection of thioacyl radicals (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/ol801219g (literal)
Alternative label
  • A. Alberti, M. Benaglia, M. Guerra, M. Gulea, D. Macciantelli, S. Masson (2008)
    On the actual EPR detection of thioacyl radicals
    in Organic letters (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • A. Alberti, M. Benaglia, M. Guerra, M. Gulea, D. Macciantelli, S. Masson (literal)
Pagina inizio
  • 3327 (literal)
Pagina fine
  • 3330 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 10 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 15 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Univ Caen Basse Normandie, ENSICAEN, LCMT, F-14050 Caen, France; ISOF CNR, Area Ric, I-40129 Bologna, Italy (literal)
Titolo
  • On the actual EPR detection of thioacyl radicals (literal)
Abstract
  • The direct EPR detection of thioacyl radicals has been reported only once, while thioacyl nitroxides remain an elusive species. We failed to detect the thioacyl radicals from two thioaldehydes and from phosphoryldithioformates but have obtained EPR evidence that thioacyl radicals react with 2-methyl-2-nitrosopropane to give thiocarbonyloxyaminyls rather than thioacyl nitroxides. The results of DFT calculations support this unexpected reactivity of thioacyls, while making questionable their previous EPR identification. (literal)
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