http://www.cnr.it/ontology/cnr/individuo/prodotto/ID51074
Densities, Viscosities, and Refractive indices of Mixtures of Poly (ethylene Glycols) + Dialkyl Carbonates at 313.15 K. (Articolo in rivista)
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- Label
- Densities, Viscosities, and Refractive indices of Mixtures of Poly (ethylene Glycols) + Dialkyl Carbonates at 313.15 K. (Articolo in rivista) (literal)
- Anno
- 2004-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/je034159d (literal)
- Alternative label
S. Ottani; D. Vitalini; F. Comelli; C. Castellari (2004)
Densities, Viscosities, and Refractive indices of Mixtures of Poly (ethylene Glycols) + Dialkyl Carbonates at 313.15 K.
in Journal of chemical and engineering data
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- S. Ottani; D. Vitalini; F. Comelli; C. Castellari (literal)
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- ISI Web of Science (WOS) (literal)
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- CNR, Istitutp per la Sintesi Organica e la Fotoreattivita', I-40126 Bologna, Italy
Universita' di Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
CNR - Istituto per la Chimica e la Tecnologia dei Polimeri, I-95125 Catania, Italy (literal)
- Titolo
- Densities, Viscosities, and Refractive indices of Mixtures of Poly (ethylene Glycols) + Dialkyl Carbonates at 313.15 K. (literal)
- Abstract
- Densities, viscosities, and refractive indices for binary systems containing mixtures of poly(ethylene glycols) at the same number-average molecular mass (M-n approximate to 300) but different polydispersities (molecular mass distribution between 1.15 and 1.98) with dimethyl carbonate or diethyl carbonate were determined at 313.15 K and at atmospheric pressure. The measurements were carried out over the whole range of composition, using a vibrating-tube density meter, Ubbelohde viscometers with a Schott-Gerate AVS 310 unit, and an Abbe refractometer. Densities, viscosities, and refractive indices were used to compute the excess volumes, V-E, viscosity deviations, Deltaeta, and deviations in molar refraction, DeltaR. Results were fitted to the Redlich-Kister polynomial, and the adjustable parameters were obtained using least-squares methods. The viscosity dependence on temperature was investigated between (309.15 and 327.15) K for some solutions in a restricted composition range. A qualitative discussion on these quantities in terms of molecular interactions is reported. (literal)
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