Densities, Viscosities, and Refractive indices of Mixtures of Poly (ethylene Glycols) + Dialkyl Carbonates at 313.15 K. (Articolo in rivista)

Type
Label
  • Densities, Viscosities, and Refractive indices of Mixtures of Poly (ethylene Glycols) + Dialkyl Carbonates at 313.15 K. (Articolo in rivista) (literal)
Anno
  • 2004-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/je034159d (literal)
Alternative label
  • S. Ottani; D. Vitalini; F. Comelli; C. Castellari (2004)
    Densities, Viscosities, and Refractive indices of Mixtures of Poly (ethylene Glycols) + Dialkyl Carbonates at 313.15 K.
    in Journal of chemical and engineering data
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • S. Ottani; D. Vitalini; F. Comelli; C. Castellari (literal)
Pagina inizio
  • 148 (literal)
Pagina fine
  • 154 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 49 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 7 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 1 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR, Istitutp per la Sintesi Organica e la Fotoreattivita', I-40126 Bologna, Italy Universita' di Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy CNR - Istituto per la Chimica e la Tecnologia dei Polimeri, I-95125 Catania, Italy (literal)
Titolo
  • Densities, Viscosities, and Refractive indices of Mixtures of Poly (ethylene Glycols) + Dialkyl Carbonates at 313.15 K. (literal)
Abstract
  • Densities, viscosities, and refractive indices for binary systems containing mixtures of poly(ethylene glycols) at the same number-average molecular mass (M-n approximate to 300) but different polydispersities (molecular mass distribution between 1.15 and 1.98) with dimethyl carbonate or diethyl carbonate were determined at 313.15 K and at atmospheric pressure. The measurements were carried out over the whole range of composition, using a vibrating-tube density meter, Ubbelohde viscometers with a Schott-Gerate AVS 310 unit, and an Abbe refractometer. Densities, viscosities, and refractive indices were used to compute the excess volumes, V-E, viscosity deviations, Deltaeta, and deviations in molar refraction, DeltaR. Results were fitted to the Redlich-Kister polynomial, and the adjustable parameters were obtained using least-squares methods. The viscosity dependence on temperature was investigated between (309.15 and 327.15) K for some solutions in a restricted composition range. A qualitative discussion on these quantities in terms of molecular interactions is reported. (literal)
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