Cis-trans Photoisomerization in [Ru(DIP)2(MeOH)2][OTf]2: synthesis, NMR, X-ray structure of the trans-isomer and photophysical properties (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Cis-trans Photoisomerization in [Ru(DIP)2(MeOH)2][OTf]2: synthesis, NMR, X-ray structure of the trans-isomer and photophysical properties (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1039/b701089c (literal)

Alternative label

• H. Amouri; J. B. Waern; R. Caspar; A. Barbieri; C. Sabatini; A. Zanelli; F. Barigelletti (2007)
  Cis-trans Photoisomerization in [Ru(DIP)2(MeOH)2][OTf]2: synthesis, NMR, X-ray structure of the trans-isomer and photophysical properties
  in Dalton transactions (2003. Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• H. Amouri; J. B. Waern; R. Caspar; A. Barbieri; C. Sabatini; A. Zanelli; F. Barigelletti (literal)

Pagina inizio

• 2179 (literal)

Pagina fine

• 2186 (literal)

Rivista

• Dalton transactions (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• In: Dalton Transactions, vol. 2007 pp. 2179 - 2186. RSC- The Royal Society of Chemistry, 2007. (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 21 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1. Univ Paris 06, UMR CNRS 7071, Lab Chim Inorgan & Mat Mol, F-75252 Paris 05, France 2. CNR, Ist Sintesi Organ & Fotoreattivita, I-40129 Bologna, Italy (literal)

Titolo

• Cis-trans Photoisomerization in [Ru(DIP)2(MeOH)2][OTf]2: synthesis, NMR, X-ray structure of the trans-isomer and photophysical properties (literal)

Abstract

• The first trans-ruthenium complex trans-[Ru(DIP)2(MeOH)2][OTf]2 (1b, where DIP = 4,7-diphenyl-1,10-phenanthroline) incorporating a -extended ligand was prepared via two methods: either photolysis of cis-[Ru(DIP)2(OTf)2] in MeOH-Et2O or via crystallization from MeOH-Et2O in direct sunlight. The X-ray molecular structure of 1b is reported and confirmed the trans geometry of the title compound. The cis-trans isomerization process was monitored by 1H-NMR and showed that 1b reverts back to cis-[Ru(DIP)2(MeOH)2][OTf]2 (1a) in methanol-d4 after 15 h at 55 °C or several days at room temperature. The absorption spectra recorded in MeOH showed a bathochromic shift of the MLCT band of the trans-isomer 1b relative to that of the cis complex 1a. Interestingly at 77 K the emission spectrum of 1b is red shifted compared to the cis analog 1a. A rational explanation in terms of the energy of the excited states in the cis- and trans-isomers is proposed to explain this behavior. (literal)

Prodotto di

• Materiali Avanzati per la COnversione di energia Luminosa (MACOL) (PM.P04.010.001) (Modulo)
• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)

Autore CNR

• ALBERTO ZANELLI (Unità di personale interno)
• ANDREA BARBIERI (Persona)
• FRANCESCO BARIGELLETTI (Unità di personale interno)
• CRISTIANA SABATINI (Unità di personale esterno)

Insieme di parole chiave

• Parole chiave di "Cis-trans Photoisomerization in [Ru(DIP)2(MeOH)2][OTf]2: synthesis, NMR, X-ray structure of the trans-isomer and photophysical properties" (Insieme di parole chiave)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Materiali Avanzati per la COnversione di energia Luminosa (MACOL) (PM.P04.010.001) (Modulo)

Autore CNR di

• FRANCESCO BARIGELLETTI (Unità di personale interno)
• ANDREA BARBIERI (Persona)
• ALBERTO ZANELLI (Unità di personale interno)
• CRISTIANA SABATINI (Unità di personale esterno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Dalton transactions (Rivista)

Insieme di parole chiave di

• Parole chiave di "Cis-trans Photoisomerization in [Ru(DIP)2(MeOH)2][OTf]2: synthesis, NMR, X-ray structure of the trans-isomer and photophysical properties" (Insieme di parole chiave)