Radical ions from and spin adducts to 1,2-dimethyl-3,4-bis[(2,4,6-tri-tert-butylphenyl) phosphinidene]-1-cyclobutene (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Radical ions from and spin adducts to 1,2-dimethyl-3,4-bis[(2,4,6-tri-tert-butylphenyl) phosphinidene]-1-cyclobutene (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1163/156856707782169363 (literal)

Alternative label

• A. Alberti, M. Benaglia, M. Guerra and D. Macciantelli (2007)
  Radical ions from and spin adducts to 1,2-dimethyl-3,4-bis[(2,4,6-tri-tert-butylphenyl) phosphinidene]-1-cyclobutene
  in Research on chemical intermediates (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• A. Alberti, M. Benaglia, M. Guerra and D. Macciantelli (literal)

Pagina inizio

• 725 (literal)

Pagina fine

• 737 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 33 (literal)

Rivista

• Research on chemical intermediates (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 8-9 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ISOF-CNR (literal)

Titolo

• Radical ions from and spin adducts to 1,2-dimethyl-3,4-bis[(2,4,6-tri-tert-butylphenyl) phosphinidene]-1-cyclobutene (literal)

Abstract

• The radical cation and anion of the title compound were obtained either by treatment with mercury trifluorocatetate in trifluoroacetic acid or by reduction with potassium in tetrahydrofurane. For both species the ESR spectra indicated magnetic non-equivalence of the two phosphorus atoms, as well as of the two methyl groups. Spectra attributed to the corresponding spin adducts were also observed when reacting the title compound with in situ-generated alkoxyl and thiyl radicals. MO calculations carried out for both the ionic radicals and the neutral spin adducts led to questioning the actual nature of some of the latter species. (literal)

Prodotto di

• Processi di polimerizzazione radicalica: polimerizzazione RAFT, applicazioni delle radiazioni ad alta energia e della spettroscopia ESR (PM.P02.015.001) (Modulo)
• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)

Autore CNR

• DANTE MACCIANTELLI (Unità di personale interno)
• ANGELO ALBERTI (Persona)
• MAURIZIO GUERRA (Persona)
• MASSIMO BENAGLIA (Persona)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Processi di polimerizzazione radicalica: polimerizzazione RAFT, applicazioni delle radiazioni ad alta energia e della spettroscopia ESR (PM.P02.015.001) (Modulo)

Autore CNR di

• MAURIZIO GUERRA (Persona)
• ANGELO ALBERTI (Persona)
• DANTE MACCIANTELLI (Unità di personale interno)
• MASSIMO BENAGLIA (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Research on chemical intermediates (Rivista)