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Electronic structures of highly-ordered films of self-assembled graphitic nano-columns (Articolo in rivista)
- Type
- Label
- Electronic structures of highly-ordered films of self-assembled graphitic nano-columns (Articolo in rivista) (literal)
- Anno
- 2003-01-01T00:00:00+01:00 (literal)
- Alternative label
R. Friedlein, X. Crispin, C.D. Simpson, M.D. Watson, F. Jäckel, W. Osikowicz, S. Marciniak, M.P. de Jong, P. Samorì, S.K.M. Jönsson, M. Fahlman, K. Müllen, J.P. Rabe, W.R. Salaneck (2003)
Electronic structures of highly-ordered films of self-assembled graphitic nano-columns
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- R. Friedlein, X. Crispin, C.D. Simpson, M.D. Watson, F. Jäckel, W. Osikowicz, S. Marciniak, M.P. de Jong, P. Samorì, S.K.M. Jönsson, M. Fahlman, K. Müllen, J.P. Rabe, W.R. Salaneck (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Note
- ISI Web of Science (WOS) (literal)
- Titolo
- Electronic structures of highly-ordered films of self-assembled graphitic nano-columns (literal)
- Abstract
- Highly ordered, several nanometers thick films of alkylated large planar, polycyclic aromatic hydrocarbon (PAH) molecules have been grown on semi-metallic molybdenum disulfide substrates. The films are characterized by a two-dimensional lateral arrangement of columns standing at the surface on a macroscopic scale.
The self-assembly of such insulated columns of face-to-face disks with surface-induced vertical alignment has been achieved directly from solution processing. Angle-resolved photoelectron spectra revealed a highly anisotropic quasi-one-dimensional electronic structure with an extended p-electronic wave function. An intermolecular dispersion of the highest occupied band of at least 0.15 eV along the stacking direction has been measured. A partial breakdown of the concept of quasimomentum due to the finite size of the nano-objects perpendicular to the stacks is observed. (literal)
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