Ordered architectures of a soluble hexabenzocoronene-pyrene dyad: thermotropic bulk properties and nanoscale phase-segregation at surfaces (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Ordered architectures of a soluble hexabenzocoronene-pyrene dyad: thermotropic bulk properties and nanoscale phase-segregation at surfaces (Articolo in rivista) (literal)

Anno

• 2003-01-01T00:00:00+01:00 (literal)

Alternative label

• N. Tchebotareva, X. Yin, M.D. Watson, P. Samorì, J.P. Rabe, K. Müllen (2003)
  Ordered architectures of a soluble hexabenzocoronene-pyrene dyad: thermotropic bulk properties and nanoscale phase-segregation at surfaces
  in Journal of the American Chemical Society (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• N. Tchebotareva, X. Yin, M.D. Watson, P. Samorì, J.P. Rabe, K. Müllen (literal)

Pagina inizio

• 9734 (literal)

Pagina fine

• 9739 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 125 (literal)

Rivista

• Journal of the American Chemical Society (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Titolo

• Ordered architectures of a soluble hexabenzocoronene-pyrene dyad: thermotropic bulk properties and nanoscale phase-segregation at surfaces (literal)

Abstract

• An alkylated hexa- peri-hexabenzocoronene with a covalently tethered pyrene unit serves as a model to study self-assembling discotic ð-system dyads both in the bulk and at a surface. Wide-angle X-ray scattering, polarized light microscopy, and differential scanning calorimetry revealed bulk self-assembly into columnar structures. Relative to a control without a tethered pyrene, the new dyad exhibits a more ordered columnar phase at room temperature but with dramatically lowered isotropization temperature, facilitating homeotropic alignment. These two features are important for processing such materials into molecular electronic devices, e.g., photovoltaic diodes. Scanning tunneling microscopy at a solution-solid interface revealed uniform nanoscale segregation of the large from the small ð-systems, leading to a well-defined two-dimensional crystalline monolayer, the likes of which may be employed in the future to study intramolecular electron transfer processes at surfaces, on the molecular scale. (literal)

Prodotto di

• MAteriali Funzionali Organici per applicazioni High-Tech: sistemi molecolari, supramolecolari e bioibridi (MAFO-HT) (PM.P04.003.003) (Modulo)
• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)

Autore CNR

• PAOLO SAMORI' (Unità di personale interno)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• MAteriali Funzionali Organici per applicazioni High-Tech: sistemi molecolari, supramolecolari e bioibridi (MAFO-HT) (PM.P04.003.003) (Modulo)

Autore CNR di

• PAOLO SAMORI' (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of the American Chemical Society (Rivista)