Synthesis and reactivities of enantiomerically pure beta-hydroxyalkyl and beta-aminoalkyl ferrocenyl sulfides (Articolo in rivista)

Type
Label
  • Synthesis and reactivities of enantiomerically pure beta-hydroxyalkyl and beta-aminoalkyl ferrocenyl sulfides (Articolo in rivista) (literal)
Anno
  • 2002-01-01T00:00:00+01:00 (literal)
Alternative label
  • Bernardi, L.; Bonini, B. F.; Comes-Franchini, M.; Fochi, M.F.; Mazzanti, G.; Ricci, A.; Varchi, G. (2002)
    Synthesis and reactivities of enantiomerically pure beta-hydroxyalkyl and beta-aminoalkyl ferrocenyl sulfides
    in European journal of organic chemistry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Bernardi, L.; Bonini, B. F.; Comes-Franchini, M.; Fochi, M.F.; Mazzanti, G.; Ricci, A.; Varchi, G. (literal)
Pagina inizio
  • 2776 (literal)
Pagina fine
  • 2784 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 16 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Titolo
  • Synthesis and reactivities of enantiomerically pure beta-hydroxyalkyl and beta-aminoalkyl ferrocenyl sulfides (literal)
Abstract
  • Enantiomerically pure beta-hydroxyalkyl and beta-aminoalkyl ferrocenyl sulfides have been synthesized in good yields from mercaptoferrocene and amino alcohol derivatives. Primary beta-aminoalkyl sulfides allowed the synthesis of tetrahydro-1,4-thiazepines containing the ferrocene moiety with good diastereoselectivity and -iminoalkyl sulfides. Some of these derivatives have successfully been employed as ligands for palladium-catalyzed allylic substitution, with asymmetric induction of up to 99% ee (literal)
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