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Synthesis and reactivities of enantiomerically pure beta-hydroxyalkyl and beta-aminoalkyl ferrocenyl sulfides (Articolo in rivista)
- Type
- Label
- Synthesis and reactivities of enantiomerically pure beta-hydroxyalkyl and beta-aminoalkyl ferrocenyl sulfides (Articolo in rivista) (literal)
- Anno
- 2002-01-01T00:00:00+01:00 (literal)
- Alternative label
Bernardi, L.; Bonini, B. F.; Comes-Franchini, M.; Fochi, M.F.; Mazzanti, G.; Ricci, A.; Varchi, G. (2002)
Synthesis and reactivities of enantiomerically pure beta-hydroxyalkyl and beta-aminoalkyl ferrocenyl sulfides
in European journal of organic chemistry (Print)
(literal)
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- Bernardi, L.; Bonini, B. F.; Comes-Franchini, M.; Fochi, M.F.; Mazzanti, G.; Ricci, A.; Varchi, G. (literal)
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- ISI Web of Science (WOS) (literal)
- Titolo
- Synthesis and reactivities of enantiomerically pure beta-hydroxyalkyl and beta-aminoalkyl ferrocenyl sulfides (literal)
- Abstract
- Enantiomerically pure beta-hydroxyalkyl and beta-aminoalkyl ferrocenyl sulfides have been synthesized in good yields from mercaptoferrocene and amino alcohol derivatives. Primary beta-aminoalkyl sulfides allowed the synthesis of tetrahydro-1,4-thiazepines containing the ferrocene moiety with good diastereoselectivity and -iminoalkyl sulfides. Some of these derivatives have successfully been employed as ligands for palladium-catalyzed allylic substitution, with asymmetric induction of up to 99% ee (literal)
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