The reaction of the organometallic acid [(h5-C5H4COOH)2CoIII]+ with HBr and HI. Preparation and characterization of [(h5-C5H4COOH)2CoIII]Br and [(h5-C5H4COOH)2CoIII]I and hydrogen bridges between cations. (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• The reaction of the organometallic acid [(h5-C5H4COOH)2CoIII]+ with HBr and HI. Preparation and characterization of [(h5-C5H4COOH)2CoIII]Br and [(h5-C5H4COOH)2CoIII]I and hydrogen bridges between cations. (Articolo in rivista) (literal)

Anno

• 2003-01-01T00:00:00+01:00 (literal)

Alternative label

• Braga, Dario; Emiliani, Dario; Cojazzi, Gianna; Maini, Lucia; Polito, Marco; Grepioni, Fabrizia (2003)
  The reaction of the organometallic acid [(h5-C5H4COOH)2CoIII]+ with HBr and HI. Preparation and characterization of [(h5-C5H4COOH)2CoIII]Br and [(h5-C5H4COOH)2CoIII]I and hydrogen bridges between cations.
  in Journal of molecular structure (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Braga, Dario; Emiliani, Dario; Cojazzi, Gianna; Maini, Lucia; Polito, Marco; Grepioni, Fabrizia (literal)

Pagina inizio

• 113 (literal)

Pagina fine

• 119 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 647 (literal)

Rivista

• Journal of molecular structure (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Titolo

• The reaction of the organometallic acid [(h5-C5H4COOH)2CoIII]+ with HBr and HI. Preparation and characterization of [(h5-C5H4COOH)2CoIII]Br and [(h5-C5H4COOH)2CoIII]I and hydrogen bridges between cations. (literal)

Abstract

• The water sol. dicarboxylic cationic acid [(h5-C5H4COOH)2CoIII]+ (1) as its Cl- salt was treated thermally to produce the neutral zwitterion [(h5-C5H4COOH)(h5-C5H4COO)CoIII] (2). 2 Reacts with HBr in water soln. to yield the bromide salt of the dicarboxylic acid [(h5-C5H4-COOH)2CoIII]Br, 1Br. Prepn. of the iodide [(h5-C5H4COOH)2CoIII]I, 1I, was achieved by direct oxidn. of [(h5-C5H4Me)2CoIII]OH with KMnO4 immediately followed by reaction with HI. The crystal structures of 1Br and 1I were detd. by single crystal x-ray diffraction. The H bonding interactions between the acid cations and between the acid cation and the halide ions were studied. (literal)

Prodotto di

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of molecular structure (Rivista)