Excess molar enthalpies of binary mixtures containing glycols or polyglycols + dimethyl sulfoxide at 308.15 K (Articolo in rivista)

Type
Label
  • Excess molar enthalpies of binary mixtures containing glycols or polyglycols + dimethyl sulfoxide at 308.15 K (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/je034007i (literal)
Alternative label
  • Comelli, F.; Ottani, S.; Francesconi, R.; Castellari C (2003)
    Excess molar enthalpies of binary mixtures containing glycols or polyglycols + dimethyl sulfoxide at 308.15 K
    in Journal of chemical and engineering data
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Comelli, F.; Ottani, S.; Francesconi, R.; Castellari C (literal)
Pagina inizio
  • 995 (literal)
Pagina fine
  • 998 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 48 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR, ISOF, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy Univ Bologna, Dipartimento Chim G Ciamician, Alma Mater Studiorum, I-40126 Bologna, Italy (literal)
Titolo
  • Excess molar enthalpies of binary mixtures containing glycols or polyglycols + dimethyl sulfoxide at 308.15 K (literal)
Abstract
  • Excess molar enthalpies, H-m(E), were determined as a function of molar fraction at 308.15 K and at atmospheric pressure for the binary mixtures containing dimethyl sulfoxide with ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, poly(ethylene glycol)-200, poly(ethylene glycol)-300, poly(ethylene glycol)-400, and poly(ethylene glycol)-600. All curves are negative over the entire composition range with minima ranging from -430 J.mol(-1) (propylene glycol) up to -1080 J.mol(-1) (poly(ethylene glycol)-600). The results were correlated using the Redlich-Kister polynomial, and the adjustable parameters were obtained by the least-squares method. The dependence of H-m(E) on mixture composition is qualitatively discussed in terms of molecular interactions. (literal)
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