http://www.cnr.it/ontology/cnr/individuo/prodotto/ID50495
N-Acylation of 4-alkylidene-beta-lactams: unexpected results (Articolo in rivista)
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- Label
- N-Acylation of 4-alkylidene-beta-lactams: unexpected results (Articolo in rivista) (literal)
- Anno
- 2003-01-01T00:00:00+01:00 (literal)
- Alternative label
Ciainelli G, Giacomini D, Gazzano M, Galletti P, Quintavalla A (2003)
N-Acylation of 4-alkylidene-beta-lactams: unexpected results
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Ciainelli G, Giacomini D, Gazzano M, Galletti P, Quintavalla A (literal)
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- ISI Web of Science (WOS) (literal)
- Titolo
- N-Acylation of 4-alkylidene-beta-lactams: unexpected results (literal)
- Abstract
- This paper describes the different reactivity of E- and Z-4-alkylidene-beta-lactams in acylation reactions under basic conditions. The E isomer is readily acylated, whereas the Z reacted sluggishly rearranging to the corresponding oxazin-6-one. The N-acylation of Z isomers was successfully obtained with oxalyl- or malonyl chlorides in benzene at reflux. (literal)
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