Immersion calorimetry as a tool to evaluate the catalytic performance of titanosilicate materials in the epoxidation of cyclohexene (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Immersion calorimetry as a tool to evaluate the catalytic performance of titanosilicate materials in the epoxidation of cyclohexene (Articolo in rivista) (literal)

Anno

• 2011-01-01T00:00:00+01:00 (literal)

Alternative label

• Vernimmen, J.; Guidotti, M.; Silvestre-Albero, J.; Jardim, E. O.; Mertens, M.; Lebedev, O. I.; Van Tendeloo, G.; Psaro, R.; Rodriguez-Reinoso, F.; Meynen, V.; Cool, P. (2011)
  Immersion calorimetry as a tool to evaluate the catalytic performance of titanosilicate materials in the epoxidation of cyclohexene
  in Langmuir
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Vernimmen, J.; Guidotti, M.; Silvestre-Albero, J.; Jardim, E. O.; Mertens, M.; Lebedev, O. I.; Van Tendeloo, G.; Psaro, R.; Rodriguez-Reinoso, F.; Meynen, V.; Cool, P. (literal)

Pagina inizio

• 3618 (literal)

Pagina fine

• 3625 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 27 (literal)

Rivista

• Langmuir (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Laboratory of Adsorption and Catalysis, Department of Chemistry, University of Antwerp, CDE, Universiteitsplein 1, B-2610 Wilrijk, Belgium. CNR-Istituto di Scienze e Tecnologie Molecolari, via G. Venezian 21, 20133 Milano, Italy. Laboratorio de Materiales Avanzados, Departamento de Quimica Inorganica - Instituto Universitario de Materiales, Universidad de Alicante, Ctra. San Vicente s/n, E-03690 Alicante, Spain. Flemish Institute for Technological Research (VITO N.V.), Boeretang 200, B-2400 Mol, Belgium. CRISMAT, UMR 6508, CNRS-ENSICAEN, 6 Bd Marechal Juin, 14050 Caen, France. EMAT, Department of Physics, University of Antwerp, CGB, Groenenborgerlaan 171, B-2020 Antwerpen, Belgium. (literal)

Titolo

• Immersion calorimetry as a tool to evaluate the catalytic performance of titanosilicate materials in the epoxidation of cyclohexene (literal)

Abstract

• Different types of titanosilicates are synthesized, structurally characterized, and subsequently catalytically tested in the liquid-phase epoxidation of cyclohexene. The performance of three types of combined zeolitic/mesoporous materials is compared with that of widely studied Ti-grafted-MCM-41 molecular sieve and the TS-1 microporous titanosilicate. The catalytic test results are correlated with the structural characteristics of the different catalysts. Moreover, for the first time, immersion calorimetry with the same substrate molecule as in the catalytic test reaction is applied as an extra means to interpret the catalytic results. A good correlation between catalytic performance and immersion calorimetry results is found. This work points out that the combination of catalytic testing and immersion calorimetry can lead to important insights into the influence of the materials structural characteristics on catalysis. Moreover, the potential of using immersion calorimetry as a screening tool for catalysts in epoxidation reactions is shown. (literal)

Prodotto di

• Catalizzatori per la produzione chemo-, regio- e stereoselettiva di fine chemicals (PM.P03.002.002) (Modulo)
• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)

Autore CNR

• MATTEO GUIDOTTI (Unità di personale interno)
• RINALDO PSARO (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Immersion calorimetry as a tool to evaluate the catalytic performance of titanosilicate materials in the epoxidation of cyclohexene" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Catalizzatori per la produzione chemo-, regio- e stereoselettiva di fine chemicals (PM.P03.002.002) (Modulo)

Autore CNR di

• RINALDO PSARO (Unità di personale interno)
• MATTEO GUIDOTTI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Langmuir (Rivista)

Insieme di parole chiave di

• Keywords of "Immersion calorimetry as a tool to evaluate the catalytic performance of titanosilicate materials in the epoxidation of cyclohexene" (Insieme di parole chiave)