Er3+ and Eu3+ complexes with heptafluoroacetylacetone and tris(pentafluoro)phenylphosphine oxide: the role of the pentafluorophenyl group on the coordination geometry and on the electronic absorption spectra (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Er3+ and Eu3+ complexes with heptafluoroacetylacetone and tris(pentafluoro)phenylphosphine oxide: the role of the pentafluorophenyl group on the coordination geometry and on the electronic absorption spectra (Articolo in rivista) (literal)

Anno

• 2011-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.ica.2010.11.010 (literal)

Alternative label

• Orbelli Biroli, A.; Pizzotti, M.; Illiano, P.; Demartin, F. (2011)
  Er3+ and Eu3+ complexes with heptafluoroacetylacetone and tris(pentafluoro)phenylphosphine oxide: the role of the pentafluorophenyl group on the coordination geometry and on the electronic absorption spectra
  in Inorganica Chimica Acta (Testo stamp.)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Orbelli Biroli, A.; Pizzotti, M.; Illiano, P.; Demartin, F. (literal)

Pagina inizio

• 254 (literal)

Pagina fine

• 261 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.sciencedirect.com/science/article/pii/S002016931000767X (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 366 (literal)

Rivista

• Inorganica Chimica Acta (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto di Scienze e Tecnologie Molecolari del CNR (CNR-ISTM), via C. Golgi 19, 20133 Milano, Italy Dip. CHimica Inorganica Metallorganica e Analitica \"Lamberto Malatesta\", Università degli Studi di Milano, via G. Venezian 21, 20133 Milano, Italy Dip. Chimica Strutturale e Stereochimica INorganica, UniVersità degli Studi di Milano, via G. Venezian 21, 20133 Milano, Italy (literal)

Titolo

• Er3+ and Eu3+ complexes with heptafluoroacetylacetone and tris(pentafluoro)phenylphosphine oxide: the role of the pentafluorophenyl group on the coordination geometry and on the electronic absorption spectra (literal)

Abstract

• In this work we report some examples of fluorinated lanthanide complexes, in which the geometry of the coordination sphere is controlled by C-F...pi system strong interactions involving the fluorinated ligands. Moreover we have also shown that a perfluorinated ligand, such as tris(pentafluorophenyl)phosphine oxide may have a role in increasing the pumping of energy, in the Er3+ complex with totally fluorinated ligands, from the p system of the perfluorinated acetylacetone ligand, acting as antenna, to the Er3+ emitting ion. (literal)

Prodotto di

• Sintesi e caratterizzazione di molecole organiche e complessi metallorganici con specifiche proprietà ottiche (PM.P04.012.002) (Modulo)
• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)

Autore CNR

• MADDALENA PIZZOTTI (Persona)
• ALESSIO ORBELLI BIROLI (Persona)

Insieme di parole chiave

• Parole chiave di "Er3+ and Eu3+ complexes with heptafluoroacetylacetone and tris(pentafluoro)phenylphosphine oxide: the role of the pentafluorophenyl group on the coordination geometry and on the electronic absorption spectra" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Sintesi e caratterizzazione di molecole organiche e complessi metallorganici con specifiche proprietà ottiche (PM.P04.012.002) (Modulo)

Autore CNR di

• MADDALENA PIZZOTTI (Persona)
• ALESSIO ORBELLI BIROLI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganica Chimica Acta (Rivista)

Insieme di parole chiave di

• Parole chiave di "Er3+ and Eu3+ complexes with heptafluoroacetylacetone and tris(pentafluoro)phenylphosphine oxide: the role of the pentafluorophenyl group on the coordination geometry and on the electronic absorption spectra" (Insieme di parole chiave)