Deposition of intact tetrairon(III) single molecule magnet monolayers on gold: an STM, XPS, and ToF-SIMS investigation (Articolo in rivista)

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  • Deposition of intact tetrairon(III) single molecule magnet monolayers on gold: an STM, XPS, and ToF-SIMS investigation (Articolo in rivista) (literal)
Anno
  • 2010-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1039/b916895h (literal)
Alternative label
  • F. Pineider; M. Mannini; C. Danieli; L. Armelao; F.M. Piras; A. Magnani; A. Cornia; R. Sessoli (2010)
    Deposition of intact tetrairon(III) single molecule magnet monolayers on gold: an STM, XPS, and ToF-SIMS investigation
    in Journal of materials chemistry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • F. Pineider; M. Mannini; C. Danieli; L. Armelao; F.M. Piras; A. Magnani; A. Cornia; R. Sessoli (literal)
Pagina inizio
  • 187 (literal)
Pagina fine
  • 194 (literal)
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  • http://pubs.rsc.org/en/Content/ArticleLanding/2010/JM/b916895h (literal)
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  • 20 (literal)
Rivista
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  • DOI: 10.1039/b916895h (literal)
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  • 1 (literal)
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
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  • 1,2,8 : La.M.M.-Department of Chemistry, INSTM Research Unit, University of Florence, Via della Lastruccia 3, 50019 Sesto Fiorentino (FI), Italy / 2 : ISTM-CNR, URT Firenze, Via della Lastruccia 3, 50019 Sesto Fiorentino (FI), Italy / 3,7 : Department of Chemistry and INSTM Research Unit, University of Modena and Reggio Emilia, Via G. Campi 183, 41100 Modena, Italy / 4: ISTM-CNR and INSTM Research Unit, Department of Chemistry, University of Padova, Via Marzolo 1, 35131 Padova, Italy / 5,6 : Department of Chemical and Biosystems Science and Technology, University of Siena, Via A. Moro 2, 53100 Siena, Italy (literal)
Titolo
  • Deposition of intact tetrairon(III) single molecule magnet monolayers on gold: an STM, XPS, and ToF-SIMS investigation (literal)
Abstract
  • The ability of a tetranuclear iron(III) single-molecule magnet functionalized with thioacetyl-terminated ligands to form monolayers on gold has been investigated by a multitechnique approach based on STM, XPS and ToF-SIMS. We discuss in detail several aspects, which are relevant to the reported observation of a memory effect on the monolayer prepared from dichloromethane (Mannini et al., Nat. Mater., 2009, 8, 194). In particular we show that the adsorbate comprises intact surface-bound Fe4 clusters as opposed to microcrystals or multilayers. The influence of the solvent used for the self assembly process on the morphology, composition and structure of the adsorbate is also studied for four different solvents (dichloromethane, n-hexane, toluene, 1,4-dioxane). (literal)
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