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Halogen bonding in metal-organic-supramolecular networks (Articolo in rivista)

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Halogen bonding in metal-organic-supramolecular networks (Articolo in rivista) (literal)

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Bertani Roberta; Sgarbossa Paolo; Venzo Alfonso; Lelj Francesco; Amati Mario; Resnati Giuseppe; Pilati Tullio; Metrangolo Pierangelo; Terraneo Giancarlo (2010)
Halogen bonding in metal-organic-supramolecular networks
in Coordination chemistry reviews (Print); Elsevier BV, Amsterdam (Paesi Bassi)
(literal)

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Bertani Roberta; Sgarbossa Paolo; Venzo Alfonso; Lelj Francesco; Amati Mario; Resnati Giuseppe; Pilati Tullio; Metrangolo Pierangelo; Terraneo Giancarlo (literal)

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1,2 : Department of Chemical Processes of Engineering, University of Padova, via F. Marzolo, 9, I-35131 Padova, Italy 3 : Istituto di Scienze e Tecnologie Molecolari del CNR (CNR-ISTM), via F. Marzolo, 9, I-35131 Padova, Italy 4,5 : Department of Chemistry, University of Basilicata, via N. Sauro 85, I-85100 Potenza, Italy 6,8,9 : NFMLab and CNSC-IIT@POLIMI: Department of Chemistry, Materials and Chemical Engineering \"Giulio Natta\", Politecnico di Milano; via Mancinelli 7;I-20131 Milano, Italy 7 : Istituto di Scienze e Tecnologie Molecolari del CNR (CNR-ISTM), Via Venezian 21, I-20133 Milano, Italy (literal)

Titolo

Abstract

Halogen bonding (XB) has been recently exploited as a significant tool for engineering crystals involving coordination and organometallic compounds as tectons. This review, in particular, focuses on extended networks based on XB between electron donor groups bound to metals and halo-pyridine and halo-tetrathiafulvalene moieties as electron acceptors. The influence of XB over the structures and the interactions between the organic frameworks and the metal centers is highlighted. The chemistry of some mononuclear systems forming XB is described in terms of tools for controlling supramolecular arrangement and chemical behaviour. Various computational studies on the energy of XB at different levels of sophistication, their advantages and limits concerning the evaluation of the interaction energy and modelling of its origin are critically surveyed. Modelling of a new example of interaction between Cp2MH2 (M = Mo, W) and CF3I is reported together with the description of the electron density of the complex analyzed in terms of the Quantum Theory of Atoms in Molecules (QTAIM) model. (literal)

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