Microanalytical identification of Pb-Sb-Sn yellow pigment in historical European paintings and its differentiation from lead tin and Naples yellows (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Microanalytical identification of Pb-Sb-Sn yellow pigment in historical European paintings and its differentiation from lead tin and Naples yellows (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.culher.2007.07.001 (literal)

Alternative label

• Hradil, D.; Grygar, T.; Hradilova, J.; Bezdicka, P.; Grunwaldova, V.; Fogas, I.; Miliani, C. (2007)
  Microanalytical identification of Pb-Sb-Sn yellow pigment in historical European paintings and its differentiation from lead tin and Naples yellows
  in Journal of cultural heritage
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Hradil, D.; Grygar, T.; Hradilova, J.; Bezdicka, P.; Grunwaldova, V.; Fogas, I.; Miliani, C. (literal)

Pagina inizio

• 377 (literal)

Pagina fine

• 386 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 8 (literal)

Rivista

• Journal of cultural heritage (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• DOI: 10.1016/j.culher.2007.07.001 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Hradil, D.; Grygar, T.; Hradilova, J.; Bezdicka, P.; Grunwaldova, V.; Fogas, I.Inst Inorgan Chem ASCR, ALMA Lab, Rez 25068, Czech Republic Miliani C. ISTM-CNR (literal)

Titolo

• Microanalytical identification of Pb-Sb-Sn yellow pigment in historical European paintings and its differentiation from lead tin and Naples yellows (literal)

Abstract

• The work is focused on identification of lead tin yellow types I and 11, Naples yellow, and also on discrimination of a less common, distinct yellow pigment, the tertiary Pb-Sb-Sn oxide. The knowledge about all those Pb-based yellows was in fact forgotten after introduction of modern synthetic yellows in 19th century. As late its in the last decade of the 20th century, the existence of Pb-Sb-Sn yellow and its production have been rediscovered, and only then it has been identified in colour layer of artworks. Pb-Sb-Sn yellow has recently been identified in colour layer of 17th century Italian paintings by Sandalinas and Ruiz-Moreno [C. Sandalinas, S. Ruiz-Moreno, Lead tin-antimony yellow, historical manufacture, molecular characterization and identification in seventeenth-century Italian paintings, Stud. Conserv. 49 (2003) 41-52], and here we report the finding of this pigment in Mid-European painting of the 18th and 19th centuries. Lead tin yellows, lead antimony yellow (Naples yellow), and lead antimony tin yellow were synthesized in laboratory following historical recipes, their colour was analyzed, and their structure was confirmed to provide a basis for their routine identification in microsamples of artworks by X-ray microdiffraction. Unequivocal identification of Pb-based yellows could help in authentication of traditional European paintings, because their use was temporally and also geographically specific. Combination of elemental microanalysis (X-ray fluorescence electron microanalysis) and X-ray powder microdiffraction were found very efficient in the microanalysis of colour layers of artworks with Pb-based yellows and their unequivocal identification. (C) 2007 Elsevier Masson SAS. All rights reserved. (literal)

Prodotto di

• Tecniche spettroscopiche avanzate per lo studio di materiali di interesse nei beni culturali: Modellistica teorica e sperimentale (PM.P07.003.004) (Modulo)
• Tecniche spettroscopiche avanzate per lo studio di materiali di interesse nei beni culturali (PM.P07.015.002) (Modulo)
• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)

Autore CNR

• COSTANZA MILIANI (Unità di personale interno)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Tecniche spettroscopiche avanzate per lo studio di materiali di interesse nei beni culturali (PM.P07.015.002) (Modulo)
• Tecniche spettroscopiche avanzate per lo studio di materiali di interesse nei beni culturali: Modellistica teorica e sperimentale (PM.P07.003.004) (Modulo)

Autore CNR di

• COSTANZA MILIANI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of cultural heritage (Rivista)