http://www.cnr.it/ontology/cnr/individuo/prodotto/ID48200
Stepwise formation of ruthenium(II) complexes by direct reaction on organized assemblies of thiol-terpyridine species on gold (Articolo in rivista)
- Type
- Label
- Stepwise formation of ruthenium(II) complexes by direct reaction on organized assemblies of thiol-terpyridine species on gold (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/cphc.200600573 (literal)
- Alternative label
Tuccitto, N., Torrisi, V., Cavazzini, M., Morotti, T., Puntoriero, F., Quici, S., Campagna, S., Licciardello, A. (2007)
Stepwise formation of ruthenium(II) complexes by direct reaction on organized assemblies of thiol-terpyridine species on gold
in ChemPhysChem (Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Tuccitto, N., Torrisi, V., Cavazzini, M., Morotti, T., Puntoriero, F., Quici, S., Campagna, S., Licciardello, A. (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- [Tuccitto, Nunzio; Torrisi, Vanna; Licciardello, Antonino] Univ Catania, Dipartimento Sci Chim, I-95125 Catania, Italy. [Cavazzini, Marco; Morotti, Tamara; Quici, Silvio] CNR, Ist Sci & Tecnol Mol, I-20133 Milan, Italy. [Puntoriero, Fausto; Campagna, Sebastiano] Univ Messina, Dipartimento Chim Inorgan Chim Analit & Chim Fis, I-98166 Messina, Italy. (literal)
- Titolo
- Stepwise formation of ruthenium(II) complexes by direct reaction on organized assemblies of thiol-terpyridine species on gold (literal)
- Abstract
- Surface-confined polypyridinebased
metal complexes are of
importance in several applications
such as solar energy conversion,
luminescent sensors
and molecular electronics[1]. Anchoring
of complexes on metal
surfaces can be obtained,
among others, via an intermediate
step involving the preparation
of a self-assembled monolayer
(SAM) with suitable functional
tail groups. The SAM can
then be used for binding the
metal complex, by a stepwise procedure involving coordination
chemistry reactions, directly at the surface. However, the
known synthetic routes for bulk preparation of metal complexes,
such as polypyridine complexes of ruthenium, osmium
and iridium (among the most interesting polypyridine metal
complexes, because of their outstanding photophysical and
redox properties)[2] are based on reaction conditions that could
be incompatible with the properties (e.g. thermal stability) of
the monolayer that acts as one of the reactants. Indeed,
whereas for example, surface-confined iron or cobalt polypyridine
complexes have been prepared by a stepwise procedure
based on suitably-derivatized surfaces,[3] analogous ruthenium
systems have been elusive up to now, in spite of the large interest
of these latter species. (literal)
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