Hybrid organic-inorganic nanostructured acrylic films based on methacylate modified zirconium oxocluster (Articolo in rivista)

Type
Label
  • Hybrid organic-inorganic nanostructured acrylic films based on methacylate modified zirconium oxocluster (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/macp.200700148 (literal)
Alternative label
  • M. Sangermano, S. Gross, L. Pracella, A. Priola, G. Rizza (2007)
    Hybrid organic-inorganic nanostructured acrylic films based on methacylate modified zirconium oxocluster
    in Macromolecular chemistry and physics (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • M. Sangermano, S. Gross, L. Pracella, A. Priola, G. Rizza (literal)
Pagina inizio
  • 1730 (literal)
Pagina fine
  • 1736 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 208 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 7 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 16 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Politecn Torino, I-10129 Turin, Italy Dipartimento Sci Mat & Ingn Chim, INSTM Unit, I-10129 Turin, Italy Univ Padua, Dipartimento Sci Chim, CNR ISTM, I-35131 Padua, Italy INSTM, I-35131 Padua, Italy Ecole Polytech, Solides Irradies Lab, CEA, DSM DRECAM CNRS UMR 7642, F-91128 Palaiseau, France (literal)
Titolo
  • Hybrid organic-inorganic nanostructured acrylic films based on methacylate modified zirconium oxocluster (literal)
Abstract
  • Organic-inorganic nanostructured acrylic films, based on methacrylate-modified zirconium oxocluster, were prepared by UV-induced polymerization, which yielded transparent and crack-free layers. TEM analysis evidenced that all the inorganic particles are well dispersed with no significant macroscopic agglomerations. FT-IR kinetic investigations showed that the presence of the zirconium oxocluster does not affect the photopolymerization rate or acrylic double bond conversion. An increase on T(g) values of the cured films is evident at 15 wt.-% load of the inorganic filler. A thermal stability increase was also achieved in the presence of the zirconium oxocluster. Surface studies performed by XPS analyses showed the presence of homogeneously distributed zirconium oxoclusters, which includes important improvements of the surface hardness evidenced on the basis of the pencil test. (literal)
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