Supramolecular rods via halogen bonding-based self-assembly of fluorinated phosphazene nanopillars (Articolo in rivista)

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  • Supramolecular rods via halogen bonding-based self-assembly of fluorinated phosphazene nanopillars (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.ica.2006.10.013 (literal)
Alternative label
  • R. Bertani; F. Chaux; M. Gleria; P. Metrangolo; R. Milani; T. Pilati; G. Resnati; M. Sansotera; A. Venzo (2007)
    Supramolecular rods via halogen bonding-based self-assembly of fluorinated phosphazene nanopillars
    in Inorganica Chimica Acta (Testo stamp.); Elsevier BV, Amsterdam (Paesi Bassi)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • R. Bertani; F. Chaux; M. Gleria; P. Metrangolo; R. Milani; T. Pilati; G. Resnati; M. Sansotera; A. Venzo (literal)
Pagina inizio
  • 1191 (literal)
Pagina fine
  • 1199 (literal)
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  • pubblicazione scientifica (literal)
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  • http://www.sciencedirect.com/science/article/pii/S0020169306006657 (literal)
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  • 360 (literal)
Rivista
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  • 9 (literal)
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
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  • 1 : Department of Chemical Engineering Processes, University of Padua, 35131 Padua, Italy / 2,4,7,8 : NFMLab - Department of Chemistry, Materials, and Chemical Engineering ''G. Natta''; Politecnico di Milano, 20131 Milan, Italy / 3,9 : Institute of Molecular Sciences and Technologies - CNR, University of Padua, Italy / 5 : Department of Chemical Sciences, University of Padua, Italy / 6 : Institute of Molecular Sciences and Technologies - CNR, University of Milan, Italy (literal)
Titolo
  • Supramolecular rods via halogen bonding-based self-assembly of fluorinated phosphazene nanopillars (literal)
Abstract
  • A cyclotriphosphazene derivative bearing six 4-iodotetrafluorophenyl-substituted arms self-assembles with dipyridyl derivatives under the control of N...I halogen bonding to give rise to complexes where the starting modules are present in a 1:3 stoichiometric ratio, respectively. The directionality of the N...I halogen bonding translates the pillar-like arrangement adopted by the cyclotriphosphazene module into the rod-shaped supramolecular structure of the formed infinite chains. The invariance of N...I interactions translates the different size of the used dipyridyl modules into different pitches along the self-assembled rods. The obtained supramolecular architec-tures show a remarkable structural similarity confirming the reliability of halogen bonding in the design of complex supramolecular networks (literal)
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