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Mononuclear nickel(II) and copper(II) complexes with Schiff base ligands derived from 2,6-diformyl-4-methylphenol and S-methylisothiosemicarbazones (Articolo in rivista)

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Mononuclear nickel(II) and copper(II) complexes with Schiff base ligands derived from 2,6-diformyl-4-methylphenol and S-methylisothiosemicarbazones (Articolo in rivista) (literal)

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Gradinaru J., Forni A., Simonov Y., Popovici M., Zecchin S., Gdaniec M., Fenton D.E. (2004)
Mononuclear nickel(II) and copper(II) complexes with Schiff base ligands derived from 2,6-diformyl-4-methylphenol and S-methylisothiosemicarbazones
in Inorganica Chimica Acta (Testo stamp.); Elsevier BV, Amsterdam (Paesi Bassi)
(literal)

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Gradinaru J., Forni A., Simonov Y., Popovici M., Zecchin S., Gdaniec M., Fenton D.E. (literal)

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http://www.sciencedirect.com.pros.lib.unimi.it/science/article/pii/S0020169304001367 (literal)

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Institute of Chemistry of the Academy of Sciences of Moldova, str. Academiei, 3, MD-2028 Chisinau, Moldova; CNR-Istituto di Scienze e Tecnologie Molecolari, via Golgi 19, I-20133 Milano, Italy; Istituto CNR per l'Energetica e le Interfasi, Corso Stati Uniti 4, I-35127 Padova, Italy; Faculty of Chemistry, A. Mickiewicz University, 60-780 Poznan, Poland; Department of Chemistry, Dainton Building, The University of Sheffield, Sheffield S3 7HF, UK (literal)

Titolo

Mononuclear nickel(II) and copper(II) complexes with Schiff base ligands derived from 2,6-diformyl-4-methylphenol and S-methylisothiosemicarbazones (literal)

Abstract

Four new square-planar Ni(II) and Cu(II) complexes with [N2O2] binding system were synthesized by metal-directed condensation of 2,6-diformyl-4-methylphenol with benzoyl or acetylacetone mono-S-methylisothiosemicarbazone. Only mononuclear \"one-armed\" complexes were obtained as a consequence of the different reactivity of the two carbonyl groups in the hydroxydialdehyde. The complexes were characterized by elemental analysis, EI MS and UV-Vis spectroscopy. The structural assignment was confirmed by X-ray diffraction analysis and NMR spectroscopy, for the Ni(II) complexes, and by ESR spectroscopy and magnetic measurements, for the Cu(II) complexes. (literal)

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