Mono-, Di-, and Trimetallic Methacrylate-Substituted Metal Oxide Clusters Derived from Hafnium Butoxide (Articolo in rivista)

Type
Label
  • Mono-, Di-, and Trimetallic Methacrylate-Substituted Metal Oxide Clusters Derived from Hafnium Butoxide (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1007/s00706-003-0031-3 (literal)
Alternative label
  • Gross S., Kickelbick G., Puchberger M., Schubert U. (2003)
    Mono-, Di-, and Trimetallic Methacrylate-Substituted Metal Oxide Clusters Derived from Hafnium Butoxide
    in Monatshefte für Chemie
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Gross S., Kickelbick G., Puchberger M., Schubert U. (literal)
Pagina inizio
  • 1053 (literal)
Pagina fine
  • 1063 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 134 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 11 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 8 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Vienna Univ Technol, Inst Mat Chem, A-1060 Vienna, Austria (literal)
Titolo
  • Mono-, Di-, and Trimetallic Methacrylate-Substituted Metal Oxide Clusters Derived from Hafnium Butoxide (literal)
Abstract
  • The methacrylate-substituted clusters Hf4O2(OMC)(12), Hf6O4(OH)(4)(OMc)(12)(BuOH), Ti4Hf4O6(OBu)(4)(OMc)(16), and Ti2Zr5HfO6(OMc)(20) (OMc = methacrylate) were prepared by reacting Hf(OBu)(4), or Hf(OBu)(4)/Ti(OBu)(4) and Hf(OBu)(4)/Zr(OBu)(4)/Ti(OBu)(4) mixtures, respectively, with methacrylic acid. All clusters were characterized by X-ray structure analyses and are basically isostructural, although hot in each case isomorphous, with the corresponding oxozirconium clusters. Low-temperature NMR studies revealed that the methacrylate ligands of Hf4O2(OMc)(12) are highly dynamic even at - 80degreesC. (literal)
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