http://www.cnr.it/ontology/cnr/individuo/prodotto/ID47530
Mono-, Di-, and Trimetallic Methacrylate-Substituted Metal Oxide Clusters Derived from Hafnium Butoxide (Articolo in rivista)
- Type
- Label
- Mono-, Di-, and Trimetallic Methacrylate-Substituted Metal Oxide Clusters Derived from Hafnium Butoxide (Articolo in rivista) (literal)
- Anno
- 2003-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1007/s00706-003-0031-3 (literal)
- Alternative label
Gross S., Kickelbick G., Puchberger M., Schubert U. (2003)
Mono-, Di-, and Trimetallic Methacrylate-Substituted Metal Oxide Clusters Derived from Hafnium Butoxide
in Monatshefte für Chemie
(literal)
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- Gross S., Kickelbick G., Puchberger M., Schubert U. (literal)
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Vienna Univ Technol, Inst Mat Chem, A-1060 Vienna, Austria (literal)
- Titolo
- Mono-, Di-, and Trimetallic Methacrylate-Substituted Metal Oxide Clusters Derived from Hafnium Butoxide (literal)
- Abstract
- The methacrylate-substituted clusters Hf4O2(OMC)(12), Hf6O4(OH)(4)(OMc)(12)(BuOH), Ti4Hf4O6(OBu)(4)(OMc)(16), and Ti2Zr5HfO6(OMc)(20) (OMc = methacrylate) were prepared by reacting Hf(OBu)(4), or Hf(OBu)(4)/Ti(OBu)(4) and Hf(OBu)(4)/Zr(OBu)(4)/Ti(OBu)(4) mixtures, respectively, with methacrylic acid. All clusters were characterized by X-ray structure analyses and are basically isostructural, although hot in each case isomorphous, with the corresponding oxozirconium clusters. Low-temperature NMR studies revealed that the methacrylate ligands of Hf4O2(OMc)(12) are highly dynamic even at - 80degreesC. (literal)
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