Photoelectron spectroscopy of Ce(eta-C5H5)(3) - Accessing two ion states on 4f ionization (Articolo in rivista)

Type
Label
  • Photoelectron spectroscopy of Ce(eta-C5H5)(3) - Accessing two ion states on 4f ionization (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.cplett.2006.10.029 (literal)
Alternative label
  • Coreno, M; de Simone, M; Green, JC; Kaltsoyannis, N; Narband, N; Sella, A (2006)
    Photoelectron spectroscopy of Ce(eta-C5H5)(3) - Accessing two ion states on 4f ionization
    in Chemical physics letters (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Coreno, M; de Simone, M; Green, JC; Kaltsoyannis, N; Narband, N; Sella, A (literal)
Pagina inizio
  • 17 (literal)
Pagina fine
  • 21 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 432 (literal)
Rivista
Note
  • Google Scholar (literal)
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Univ Oxford, Dept Chem, Oxford OX1 3QR, England; CNR, IMIP, GasPhase, BeamlineElettra & Monterotondo, I-00016 Monterotondo, Italy; CNR, INFM, Lab Nazl, TASC, I-34012 Trieste, Italy; Univ Coll London, Dept Chem, London WC1H 0AJ, England (literal)
Titolo
  • Photoelectron spectroscopy of Ce(eta-C5H5)(3) - Accessing two ion states on 4f ionization (literal)
Abstract
  • Valence PES have been measured for Ce(eta-C5H5)(3) in the gas phase with photon energies of 24-135 eV. Two ion states arising from ionization of the single 4f electron are unambiguously characterized by the intensity behaviour of the associated bands. Assignment is made using a VBCI model where purely ionic components are allowed to mix under configuration interaction. Thus the ground state of the [Ce(eta-C5H5)(3)](+) cation is described as a mixture of two configurations of (1)A(1) symmetry, one with no 4f electron, Lf(0) and one with a single 4f electron interacting strongly with a hole of the same symmetry in the ligand shell, L-T. (c) 2006 Elsevier B.V. All rights reserved. (literal)
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